Improvements of Interfacial and Electrical Properties for Ge MOS Capacitor with LaTaON Gate Dielectric by Optimizing Ta Content
Bin-Xu, Jing-Ping Xu, Lu Liu** , Yong Su
School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074
Abstract :The interfacial and electrical properties of high-$k$ LaTaON gate dielectric Ge metal-oxide-semiconductor (MOS) capacitors with different tantalum (Ta) contents are investigated. Experimental results show that the Ge MOS capacitors with a Ta content of $\sim$30% exhibit the best interfacial and electrical properties, including low interface-state density $(7.6\times10^{11}$ cm$^{-2}$ eV$^{-1}$), small gate-leakage current $(8.32\times10^{-5}$ A/cm$^{2}$) and large equivalent permittivity (22.46). The x-ray photoelectron spectroscopy results confirm that the least GeO$_{x}$ is formed at the Ge surface for the sample with a Ta content of $\sim$30% due to the effective blocking role of Ta against O diffusion and the greatly improved hygroscopicity of LaON.
收稿日期: 2018-01-29
出版日期: 2018-06-24
:
73.40.Qv
(Metal-insulator-semiconductor structures (including semiconductor-to-insulator))
73.20.At
(Surface states, band structure, electron density of states)
71.20.Eh
(Rare earth metals and alloys)
[1] Kamata Y 2008 Mater. Today 11 30 [2] Caymax M, Houssa M, Pourtois G, Bellenger F, Martens K, Delabie A and van Elshocht S 2008 Appl. Surf. Sci. 254 6094 [3] Abermann S, Henkel C, Bethge O, Pozzovivo G, Klang P and Bertagnolli E 2010 Appl. Surf. Sci. 256 5031 [4] Xu H X, Xu J P, Li C X and Lai P T 2010 Appl. Phys. Lett. 97 022903 [5] Mavrou G, Tsipas P, Sotiropoulos A, Galata S, Panayiotatos Y, Dimoulas A, Marchiori C and Fompeyrine J 2008 Appl. Phys. Lett. 93 212904 [6] Molle A, Baldovino S, Fanciulli M, Tsoutsou D, Golias E and Dimoulas A 2011 J. Appl. Phys. 110 084504 [7] Lin M H, Lan C K, Chen C C and Wu J Y 2011 Appl. Phys. Lett. 99 182105 [8] Liu L N, Choi H W, Xu J P and Lai P T 2015 Appl. Phys. Lett. 107 213501 [9] Ji F, Xu J P, Huang Y, Liu L and Lai P T 2014 IEEE Trans. Electron Devices 61 3608 [10] Cheng Z X, Xu J P, Liu L, Huang Y, Lai P T and Tang W M 2016 Appl. Phys. Lett. 109 023514 [11] Cheng Z X 2017 PhD Dissertation (Wuhan: Huazhong University of Science and Technology) (in Chinese) [12] Huang X D, Sin J K O and Lai P T 2012 IEEE Trans. Device Mater. Reliab. 12 306 [13] Hagiwara H, Nagatomo M, Seto C, Ida S and Ishiahara T 2013 Catalysts 3 614 [14] Crist B V 1999 Handbook of Monochromatic XPS Spectra: The Elements of Native Oxides (Chichester: Wiley) [15] Gao Q, Wang S, Ma Y, Tang Y, Giordano C and Antonietti M 2012 Angew. Chem. Int. Ed. 51 961 [16] Sekhar M C, Uthanna S, Martins R, Chandra S J and Elangovan E 2012 IOP Conf. Ser.: Mater. Sci. Eng. 34 012009 [17] Chun W J, Ishikawa A, Fujisawa H, Takata T, Kondo J N, Hara M, Kawai M, Matsumoto Y and Domen K 2003 J. Phys. Chem. B 107 1798 [18] Molle A, Bhuiyan M N K, Tallarida G and Fanciulli M 2006 Appl. Phys. Lett. 89 083504 [19] Ko T S, Shieh J, Yang M C, Lu T C, Kuo H C and Wang S C 2008 Thin Solid Films 516 2934 [20] Perego M, Scarel G, Fanciulli M, Fedushkin I L and Skatova A A 2007 Appl. Phys. Lett. 90 162115 [21] Xie Q, Deng S, Schaekers M, Lin D, Caymax M, Delabie A, Qu X P, Jiang Y L, Deduytsche D and Detavernier C 2012 Semicond. Sci. Technol. 27 074012 [22] Dimoulas A, Tsoutsou D, Panayiotatos Y, Sotiropoulos A, Mavrou G, Galata S F and Golias E 2010 Appl. Phys. Lett. 96 012902 [23] Xu J P, Lai P T, Li C X, Zou X and Chan C L 2006 IEEE Electron Device Lett. 27 439 [24] Terman L M 1962 Solid-State Electron. 5 285 [25] Zhang L, Li H, Guo Y, Tang K, Woicik J, Robertson J and McIntyre P C 2015 ACS Appl. Mater. Interfaces 7 20499
[1]
. [J]. 中国物理快报, 2020, 37(7): 77302-.
[2]
. [J]. 中国物理快报, 2019, 36(6): 67301-.
[3]
. [J]. 中国物理快报, 2018, 35(9): 98502-.
[4]
. [J]. 中国物理快报, 2018, 35(5): 57302-.
[5]
. [J]. 中国物理快报, 2018, 35(4): 46102-.
[6]
. [J]. 中国物理快报, 2018, 35(4): 48502-.
[7]
. [J]. 中国物理快报, 2018, 35(2): 27302-.
[8]
. [J]. 中国物理快报, 2017, 34(9): 97304-.
[9]
. [J]. 中国物理快报, 2017, 34(5): 57301-.
[10]
. [J]. 中国物理快报, 2017, 34(4): 47303-047303.
[11]
. [J]. 中国物理快报, 2017, 34(1): 18501-018501.
[12]
. [J]. 中国物理快报, 2016, 33(09): 97101-097101.
[13]
. [J]. 中国物理快报, 2016, 33(07): 76102-076102.
[14]
. [J]. 中国物理快报, 2016, 33(03): 38502-038502.
[15]
. [J]. 中国物理快报, 2015, 32(12): 127101-127101.