Raman Spectroscopy and Magnetic Properties of Mn-Doped ZnO Bulk Single Crystal
HE Qing-Bo 1, 2, XU Jia-Yue1, LI Xin-Hua 1,2, A. Kamzin3, L. Kamzina3
1Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 2000502Graduate School of the Chinese Academy of Sciences, Beijing 1000493Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. Petersburg, Russia 194021
Raman Spectroscopy and Magnetic Properties of Mn-Doped ZnO Bulk Single Crystal
HE Qing-Bo 1;2;XU Jia-Yue1;LI Xin-Hua 1,2;A. Kamzin3;L. Kamzina3
1Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 2000502Graduate School of the Chinese Academy of Sciences, Beijing 1000493Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. Petersburg, Russia 194021
摘要Mn doped ZnO bulk single crystals are grown by the modified Bridgman method. The as-grown crystals are red in colour. The additional Raman mode observed at 524cm-1 is attributed to the Mn ions incorporating into ZnO crystal. The crystal exhibited paramagnetic under lower applied field below 2280Oe. Then diamagnetism is observed in the crystal when the magnetic field rises up and becomes dominant under applied field above 5270Oe. The magnetic susceptibility dependence on the temperature follows a Curie law indicating a typical paramagnetic characteristic under an applied field of 2kOe. No ferromagnetic ordering is observed in the as-grown Mn-doped ZnO crystal.
Abstract：Mn doped ZnO bulk single crystals are grown by the modified Bridgman method. The as-grown crystals are red in colour. The additional Raman mode observed at 524cm-1 is attributed to the Mn ions incorporating into ZnO crystal. The crystal exhibited paramagnetic under lower applied field below 2280Oe. Then diamagnetism is observed in the crystal when the magnetic field rises up and becomes dominant under applied field above 5270Oe. The magnetic susceptibility dependence on the temperature follows a Curie law indicating a typical paramagnetic characteristic under an applied field of 2kOe. No ferromagnetic ordering is observed in the as-grown Mn-doped ZnO crystal.
HE Qing-Bo;;XU Jia-Yue;LI Xin-Hua;A. Kamzin;L. Kamzina. Raman Spectroscopy and Magnetic Properties of Mn-Doped ZnO Bulk Single Crystal[J]. 中国物理快报, 2007, 24(12): 3499-3501.
HE Qing-Bo, XU Jia-Yue, LI Xin-Hua, A. Kamzin, L. Kamzina. Raman Spectroscopy and Magnetic Properties of Mn-Doped ZnO Bulk Single Crystal. Chin. Phys. Lett., 2007, 24(12): 3499-3501.
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