摘要Highly oriented aluminium nitride (AlN) films are grown on p-Si (100) substrates by pulsed laser deposition, and their characteristics of structure and composition are studied by x-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy. The results show that the deposited films exhibit good crystalline properties with a sharp x-ray diffraction peak at 2θ=33.15°corresponding to AlN h<100> crystalline orientation. The influences of substrate temperature and ambient nitrogen (N2) pressure on the crystallinity of AlN films are remarkable. At room temperature, when the ambient N2 pressure arises from 5×10-6 Pa to 5Pa, the crystallinity of the film becomes better. When the substrate temperature is 600°C, the film has the best crystallinity at 0.05Pa. Furthermore, the effects of substrate temperature and ambient N2 pressure on the combination of Al-N bonds and surface morphology of AlN films are also studied.
Abstract:Highly oriented aluminium nitride (AlN) films are grown on p-Si (100) substrates by pulsed laser deposition, and their characteristics of structure and composition are studied by x-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy. The results show that the deposited films exhibit good crystalline properties with a sharp x-ray diffraction peak at 2θ=33.15°corresponding to AlN h<100> crystalline orientation. The influences of substrate temperature and ambient nitrogen (N2) pressure on the crystallinity of AlN films are remarkable. At room temperature, when the ambient N2 pressure arises from 5×10-6 Pa to 5Pa, the crystallinity of the film becomes better. When the substrate temperature is 600°C, the film has the best crystallinity at 0.05Pa. Furthermore, the effects of substrate temperature and ambient N2 pressure on the combination of Al-N bonds and surface morphology of AlN films are also studied.
LV Lei;LI Qing-Shan;LI Li;ZHANG Li-Chun; WANG Cai-Feng;QI Hong-Xia. Effects of Substrate Temperature and Nitrogen Pressure on Growth of AlN Films by Pulsed Laser Deposition[J]. 中国物理快报, 2007, 24(2): 552-554.
LV Lei, LI Qing-Shan, LI Li, ZHANG Li-Chun, WANG Cai-Feng, QI Hong-Xia. Effects of Substrate Temperature and Nitrogen Pressure on Growth of AlN Films by Pulsed Laser Deposition. Chin. Phys. Lett., 2007, 24(2): 552-554.
[1] Morkoc H, Strite S, Gao G B, Lin M E, Sverdlov B and Burns M 1994 J. Appl. Phys. 76 1363 [2] Vispute R D, Narayan J, Wu H and Jagannadham K 1995 J. Appl.Phys. 77 4724 [3] Moore W J, Freitas J A, Holm R T, Kovalenkov O and Dmitriev V 2005 Appl. Phys. Lett. 86 141912 [4] Liu F S, Liu Q L, Liang J K, Luo J, Zhang H R, Zhang Y, Sun B J andRao G H 2006 J. Appl. Phys. 99 053515 [5] Chen S W, Lin H F, Sung T T, Wu J D, Kao H L and Chen J S 2003 Electron. Lett. 39 1691 [6] Ni X F, Zhu L P, Ye Z Z, Zhao Z, Tang H P, Hong W and Zhao B H 2005 Surface Coatings Technol. 198 350 [7] Hirato K, Fujioka H, Ito S, Ohta J and Oshima M 2003 ThinSolid Films 435 131 [8] Kaya K, Takahashi H, Shibata Y, Kanno Y and Hirai1 T 1997 Jpn.J. Appl. Phys. 36 2837 [9] Dovidenko K, Oktyabrsky S and Narayan J 1997 J. Appl. Phys. 82 4296 [10] Xi D J, Zheng Y D, Chen P, Zhao Z M, Chen P, Xie S Y, Jiang R L,Shen B, Gu S L and Zhang R 2002 Chin. Phys. Lett. 19 543 [11] Torres V M, Edwards J L, Wilkens B J, Smith D J, Doak R B andTsong I S T 1999 Appl. Phys. Lett. 74 985 [12] Onojima N, Suda J and Matsunami H 2002 Appl. Phys. Lett. 80 76 [13] Lin W T, Meng L C, Chen G J and Liu H S 1995 Appl. Phys.Lett. 66 2066 [14] Gyorgy E, Ristoscu C, Mihailescu I N, Klini A, Vainos N, FotakisC, Ghica C, Schmerber G and Faerber J 2001 J. Appl. Phys. 90 456 [15] Ristoscu C, Ducu C, Socol G, Craciunoiu F and Mihailescu I N 2005 Appl. Surf. Sci. 248 411 [16] Ito S, Fujioka H, Ohta J, Takahashi H and Oshima M 2003 ThinSolid Films 435 215 [17] Okamoto K, Inoue S, Matsuki N, Kim T W, Fujioka H and Oshima M2005 Phys. Status Solidi A 202 R149 [18] Inoue S, Okamoto K, Matsuki N, Kim T W and Fujioka H 2006 J.Crystal Growth 289 574 [19] Cullity B 1955 Elements of X-ray Diffraction (London:Addison-Wesley) chap 3