摘要LiSrBO3:Eu3+ phosphor is synthesized by a high solid-state reaction method, and its luminescent characteristics are investigated. The emission and excitation spectra of LiSrBO3:Eu3+ phosphors exhibit that the phosphors can be effectively excited by near ultraviolet (401nm) and blue (471nm) light, and emit 615nm red light. The effect of Eu3+ concentration on the emission spectrum of LiSrBO3:Eu3+ phosphor is studied; the results show that the emission intensity increases with increasing Eu3+ concentration, and then decreases because of concentration quenching. It reaches the maximum at 3mol%, and the concentration self-quenching mechanism is the dipole-dipole interaction according to the Dexter theory. Under the conditions of charge compensation Li+, Na+ or K+ incorporated in LiSrBO3, the luminescent intensities of LiSrBO3:Eu3+ phosphor are enhanced.
Abstract:LiSrBO3:Eu3+ phosphor is synthesized by a high solid-state reaction method, and its luminescent characteristics are investigated. The emission and excitation spectra of LiSrBO3:Eu3+ phosphors exhibit that the phosphors can be effectively excited by near ultraviolet (401nm) and blue (471nm) light, and emit 615nm red light. The effect of Eu3+ concentration on the emission spectrum of LiSrBO3:Eu3+ phosphor is studied; the results show that the emission intensity increases with increasing Eu3+ concentration, and then decreases because of concentration quenching. It reaches the maximum at 3mol%, and the concentration self-quenching mechanism is the dipole-dipole interaction according to the Dexter theory. Under the conditions of charge compensation Li+, Na+ or K+ incorporated in LiSrBO3, the luminescent intensities of LiSrBO3:Eu3+ phosphor are enhanced.
LI Pan-Lai;WANG Zhi-Jun;YANG Zhi-Ping;GUO Qing-Lin. Luminescent Characteristics of LiSrBO3:Eu3+ Phosphor for White Light Emitting Diode[J]. 中国物理快报, 2009, 26(4): 47801-047801.
LI Pan-Lai, WANG Zhi-Jun, YANG Zhi-Ping, GUO Qing-Lin. Luminescent Characteristics of LiSrBO3:Eu3+ Phosphor for White Light Emitting Diode. Chin. Phys. Lett., 2009, 26(4): 47801-047801.
[1] Kim J S et al 2004 Appl. Phys. Lett. 84 2931 [2] Lakshminarasimhan N and Varadaraju U V 2005 J.Electrochemical Soc. 152 H152 [3] Li P L et al 2008 Chin. Sci. Bull. 53 974 [4] Nakamura S and Fasol G 1997 The Blue Laser Diode(Berlin: Springer) p 1 [5] Li P L et al 2007 Chin. Phys. Lett. 24 2977 [6] Hu Y S et al 2005 J. Alloys Comp. 390 226 [7] Zhang X M, Liang L F, Zhang J H and Su Q 2005 Mater.Lett. 59 749 [8] Li P L et al 2008 J. Rare Earths 26 44 [9] Cheng W D, Zhang H, Lin Q S, Zheng F K and Chen J T 2001 Chem. Mater. 13 1841 [10] Dexter D L 1954 J. Chem. Phys. 22 1063 [11] Yu X B, Xu X L, Zhou C L, Tang J F, Peng X D and Yang S P2006 Mater. Res. Bull. 41 1578 [12] Tian L H and Mho S I 2003 Solid State Commun. 125 647