Microstructure and Corrosion Performance of Carbonitriding Layers on Cast Iron by Plasma Electrolytic Carbonitriding
PANG Hua1, LV Guo-Hua1, CHEN Huan1, WANG Xin-Quan3, ZHANG Gu-Ling4, YANG Si-Ze1,2
1Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 1001902Fujian Key Laboratory for Plasma and Magnetic Resonance, Department of Aeronautics, School of Physics and Mechanical and Electrical Engineering, Xiamen University, Xiamen 3610053College of Science, Changchun University of Science and Technology, Changchun 1300224College of Science, Central University for Nationalities, Beijing 100081
Microstructure and Corrosion Performance of Carbonitriding Layers on Cast Iron by Plasma Electrolytic Carbonitriding
PANG Hua1, LV Guo-Hua1, CHEN Huan1, WANG Xin-Quan3, ZHANG Gu-Ling4, YANG Si-Ze1,2
1Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 1001902Fujian Key Laboratory for Plasma and Magnetic Resonance, Department of Aeronautics, School of Physics and Mechanical and Electrical Engineering, Xiamen University, Xiamen 3610053College of Science, Changchun University of Science and Technology, Changchun 1300224College of Science, Central University for Nationalities, Beijing 100081
摘要The surface carbonitriding of cast iron is investigated in an aqueous solution of acetamide and glycerin. Microstructure, chemical and phase composition and corrosion performance of the carbonitriding layers are investigated by scanning electron microscopy, energy dispersive spectroscopy and x-ray diffraction, as well as potentiodynamic polarization testing. X-ray diffraction results show that the carbonitriding coatings are composed of martensite, austenite(γ-Fe), Fe2C, Fe3C, Fe5C2, FeN and ε-Fe2-3N. After the plasma electrolytic carbonitriding treatment the corrosion resistance of cast iron is clearly improved compared to the substrate, and the coatings produced at 350V for 30s give the best corrosion resistance.
Abstract:The surface carbonitriding of cast iron is investigated in an aqueous solution of acetamide and glycerin. Microstructure, chemical and phase composition and corrosion performance of the carbonitriding layers are investigated by scanning electron microscopy, energy dispersive spectroscopy and x-ray diffraction, as well as potentiodynamic polarization testing. X-ray diffraction results show that the carbonitriding coatings are composed of martensite, austenite(γ-Fe), Fe2C, Fe3C, Fe5C2, FeN and ε-Fe2-3N. After the plasma electrolytic carbonitriding treatment the corrosion resistance of cast iron is clearly improved compared to the substrate, and the coatings produced at 350V for 30s give the best corrosion resistance.
PANG Hua;LV Guo-Hua;CHEN Huan;WANG Xin-Quan;ZHANG Gu-Ling;YANG Si-Ze;. Microstructure and Corrosion Performance of Carbonitriding Layers on Cast Iron by Plasma Electrolytic Carbonitriding[J]. 中国物理快报, 2009, 26(8): 86805-086805.
PANG Hua, LV Guo-Hua, CHEN Huan, WANG Xin-Quan, ZHANG Gu-Ling, YANG Si-Ze,. Microstructure and Corrosion Performance of Carbonitriding Layers on Cast Iron by Plasma Electrolytic Carbonitriding. Chin. Phys. Lett., 2009, 26(8): 86805-086805.
[1] Jeong J J, Jeong B Y, Kim M H and Lee C 2002 Surf.Coat. Technol. 150 24 [2] Baranowska J 1998 Surf. Coat. Technol. 100--101 271 [3] Li C X and Bell T 2004 Wear 256 1144 [4] Yeroklin A L, Nie X, Leyland A, Dowey S J and Mathews A1999 Surf. Coat. Technol. 122 73 [5] Nie X, Hao Q K and Wei J M 1996 J. Wuhan Univ.Technol. Mater. Sci. Edi. 11 28 [6] Nie X, Tsotsos C, Wilson A, Yeroklin A L, Leyl A andMathews A 2001 Surf. Coat. Technol. 139 135 [7] Luk S F, Leung T P, Miu W S and Pashby I 1999 Mater.Charact. 42 65 [8] Luk S F, Leung W S, Miu W S and Pashby I 1998 J.Mater. Process Technol. 84 189 [9] Luk S F, Leung T P, Miu W S and Pashby I 1998 J.Mater. Process Technol. 91 245 [10] Nie X, wang L, Yao Z C, Zhang L and Cheng F 2005 Surf. Coat. Technol. 2001 745 [11] Shen D J, Wang Y L, Nash P and Xing G Z 2007 Materials Science and Engineering A 458 240 [12] Leyland A, Lewis D B, Stevenson P R and Matthews A 1993 Surf. Coat. Technol. 62 608 [13] Samandi M, Shedden B A, Bell T, Collins G A, Hutchings Rand Tendys J 1994 J. Vac. Sci. Technol. B 12 935 [14] Marchev K, Landis M, Vallerio R, Cooper C V and Giessen BC 1999 Surf. Coat. Technol. 116--119 184 [15] Mandl S, Gunzel R, Richter E and Moller W 1998 Surf.Coat. Technol. 100--101 372