摘要The reaction mechanism and simulations of the metal-organic chemical vapor deposition reactor for ZnO film growth are presented, indicating the temperature of the reaction species. The gas phase pre-reaction can be modulated by several factors or conditions. Simulations verify the relationships between temperature and pyrolysis of precursors, and further reveal that the substrate temperature and flow rate of cooling water have great impacts on the temperature distribution. The experimental results agree with the simulations.
Abstract:The reaction mechanism and simulations of the metal-organic chemical vapor deposition reactor for ZnO film growth are presented, indicating the temperature of the reaction species. The gas phase pre-reaction can be modulated by several factors or conditions. Simulations verify the relationships between temperature and pyrolysis of precursors, and further reveal that the substrate temperature and flow rate of cooling water have great impacts on the temperature distribution. The experimental results agree with the simulations.
ZHU Guang-Yao;GU Shu-Lin**;ZHU Shun-Ming;TANG Kun;YE Jian-Dong;ZHANG Rong;SHI Yi;ZHENG You-Dou
. Simulation and Suppression of the Gas Phase Pre-reaction in Metal-Organic Chemical Vapor Deposition of ZnO[J]. 中国物理快报, 2011, 28(11): 116803-116803.
ZHU Guang-Yao, GU Shu-Lin**, ZHU Shun-Ming, TANG Kun, YE Jian-Dong, ZHANG Rong, SHI Yi, ZHENG You-Dou
. Simulation and Suppression of the Gas Phase Pre-reaction in Metal-Organic Chemical Vapor Deposition of ZnO. Chin. Phys. Lett., 2011, 28(11): 116803-116803.
[1] Look D C et al 1998 Solid State Commun. 105 399
[2] Behrends A et al 2009 Microelectron. J. 40 280
[3] Thrush E J and Boyd A R 2006 III-Nitride Semiconductor Material (London: Imperial College Press) p 73
[4] Pawlowski R P et al 2000 J. Cryst. Growth 221 622
[5] Qian F et al 2005 Nano Lett. 5 2287
[6] Dai J N, Liu H C, Fang W Q, Wang L, Pu Y, Chen Y F and Jiang F Y 2005 J. Cryst. Growth 283 93
[7] Bagnall D M, Chen Y F, Shen M Y, Zhu Z, Goto T and Yao T 1998 J. Cryst. Growth 184/185 605
[8] Lienhard J H IV and Lienhard J H V 2003 A Heat Transfer Textbook 3rd edn (Cambridge: Phlogiston Press) p 19
[9] Liu J G, Gu S L, Zhu S M, Tang K, Liu X D, Chen H and Zheng T D 2010 J. Cryst. Growth 312 2710
[10] Dumont H, Marbeuf A, Bouree J E and Gorochov O 1993 J. Mater. Chem. 3 1075
[11] Sokolovskii A E and Baev A K 1995 Russ. J. Gen. Chem. 65 674
[12] Roth A P and Williams D F 1981 J. Appl. Phys. 52 6685
[13] Patnaik S, Huh J S and Jenson K F 1992 The 6th International Conference on Metal-organic Vapor Phase Epitaxy (Cambridge, USA 8–11 June 1992) p 250
[14] Thiandoume C, Sallet V, Triboulet R and Gorochov O 2009 J. Cryst. Growth 311 1411
[15] Fan G, Maung N, Ng T L, Williams J O and Wright A C 1995 J. Chem. Soc. Faraday Trans. 91 3475
[16] Dunlop A N and Price S J 1970 Can. J. Chem. 48 3205
[17] Price S J Wand Trotman-Dickenson A F 1957 Trans. Faraday Soc. 53 1208
[18] Lewis K G and Stimson V R 1960 J. Chem. Soc. 3087
[19] Barnard J A 1959 Trans. Faraday Soc. 55 947
[20] Lewis D, Keil M and Sarr M 1974 J. Am. Chem. Soc. 96 4398
[21] Newman C G, O'Neal H E, Ring M A, Leska F and Shipley N 1979 Int. J. Chem. Kinet. 11 1167
[22] Tsang W 1964 J. Chem. Phys. 40 1498