| FUNDAMENTAL AREAS OF PHENOMENOLOGY(INCLUDING APPLICATIONS) |
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Determination of Temperatures Using CH Radical Emission Spectroscopy |
| YANG Qian-Suo**, SONG Jun-Hao, ZHU Nai-Yi |
State Key Laboratory of High Temperature Gas Dynamics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190
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| Cite this article: |
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YANG Qian-Suo, SONG Jun-Hao, ZHU Nai-Yi 2012 Chin. Phys. Lett. 29 104707 |
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Abstract An improved Boltzmann plot method where the intensity is taken as the integral of the experimental spectrum within a special band for a cluster of a rotational line of R and Q branches is proposed. This method aims at deducing rotational and vibrational temperatures using CH radical A2Δ →X2Π band emission spectroscopy accurately. In addition, the data relative to the rotation lines of CH (A2Δ →X2Π) for both temperatures are assembled. The emission spectrum of CH (A2Δ →X2Π) at the inner cone of an acetylene-oxygen flame in a rich oxygen state is recorded and both of the temperatures are determined by the above-mentioned method. The values are recorded as 3141 K and 3097 K, for the rotational and vibrational temperatures, respectively. This result reveals that the equilibrium between the rotation and vibration states is achieved. A simple discussion for this method is also provided.
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Received: 16 July 2012
Published: 01 October 2012
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