CONDENSED MATTER: STRUCTURE, MECHANICAL AND THERMAL PROPERTIES |
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Structural and Magnetic Studies of Zn0.95Co0.05O and Zn0.90Co0.05Al0.05O |
Murtaza Saleem1**, Saadat A. Siddiqi1,2, Shahid Atiq1, M. Sabieh Anwar3
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1Centre of Excellence in Solid State Physics, University of the Punjab, Quaid-e-Azam Campus, Lahore-54590, Pakistan
2Interdisciplinary Research Centre in Biomedical Materials (IRCBM), COMSATS Institute of Information Technology, Defence Road, Off Raiwind Road, Lahore, Pakistan
3 School of Science and Engineering (SSE), Lahore University of Management Sciences (LUMS), Opposite Sector U, D.H.A. Lahore-54792, Pakistan
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Cite this article: |
Murtaza Saleem, Saadat A. Siddiqi, Shahid Atiq et al 2011 Chin. Phys. Lett. 28 116103 |
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Abstract Single-phase Zn0.95Co0.05O and Zn0.90Co0.05Al0.05O samples were prepared by a novel combustion method. X-ray diffraction studies exhibit the pure phase wurtzite structure of doped ZnO. Energy dispersive x-ray analysis confirms the incorporation of dopants into the host material. Scanning electron microscopy shows the ordered morphology in both of the samples. Temperature-dependent resistivity analysis describes the expected semiconducting behavior that is similar to the parent ZnO materials. Room-temperature magnetic measurements reveal the absence of ferromagnetism in Co-doped ZnO, while the Co and Al co-doped sample displays apparent room-temperature ferromagnetic behavior. The decrease of resistivity and presence of ferromagnetic behavior in Al-doped ZnCoO system corroborate the significant role of free carriers.
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Keywords:
61.46.Hk
75.50.Pp
47.70.Pq
75.75.-c
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Received: 08 July 2011
Published: 30 October 2011
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