Chin. Phys. Lett.  2010, Vol. 27 Issue (4): 047203    DOI: 10.1088/0256-307X/27/4/047203
CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES |
Long-Lasting Phosphorescence Properties of Pyrochlore La2Ti2O7:Pr3+ Phosphor

CHU Ming-Hui1,2, JIANG Da-Peng1, ZHAO Cheng-Jiu1, LI Bin1

1Key Laboratory of Excited State Processes, ChangchunInstitute of Optics Fine Mechanics and Physics, Chinese Academy ofSciences, Changchun 1300332Graduate School of the Chinese Academy of Sciences, Beijing 100049
Cite this article:   
CHU Ming-Hui, JIANG Da-Peng, ZHAO Cheng-Jiu et al  2010 Chin. Phys. Lett. 27 047203
Download: PDF(761KB)  
Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks
Abstract

The La2Ti2O7:Pr3+, which emits red color luminescence upon UV light excitation, is prepared by the conventional high-temperature solid-state method and its luminescent properties are systematically investigated. X-ray diffraction, photoluminescence, afterglow emission spectra and long-lasting phosphorescence (LLP) decay curves are used to characterize this phosphor. After irradiation by a 290-nm UV light for 3 min, the Pr3+-doped La2Ti2O7 phosphor emits intense red emitting afterglow from the 1D2→3H4 transitions, and its afterglow can be seen with the naked eye in the dark clearly for more than 1 h after removal of the excitation source. The afterglow decay curve of the Pr3+-doped La2Ti2O7 phosphor contains a fast decay component and another slow decay one. The possible mechanism of this red light emitting LLP phosphor is also discussed based on the experimental results.

Keywords: 72.20.Jv      78.55.Hx      78.60.Lc     
Received: 05 January 2010      Published: 27 March 2010
PACS:  72.20.Jv (Charge carriers: generation, recombination, lifetime, and trapping)  
  78.55.Hx (Other solid inorganic materials)  
  78.60.Lc (Optically stimulated luminescence)  
TRENDMD:   
URL:  
https://cpl.iphy.ac.cn/10.1088/0256-307X/27/4/047203       OR      https://cpl.iphy.ac.cn/Y2010/V27/I4/047203
Service
E-mail this article
E-mail Alert
RSS
Articles by authors
CHU Ming-Hui
JIANG Da-Peng
ZHAO Cheng-Jiu
LI Bin
[1] Chen D and Xu R 1998 Mater. Res. Bull. 33 409
[2] Li K et al 2006 Nanotechnology 17 4863
[3] Hwang D et al 2003 J. Phys. Chem. B 107 4963
[4] Joseph L et al 2008 Spectrochim. Acta A 71 1281
[5] Diallo P T et al 1998 J. Alloys Compd. 275--277 307
[6] Diallo P T et al 2002 J. Alloys Compd. 341 139
[7] Park J K et al 2001 J. Mater. Res . 16 2568
[8] Pinel E et al 2004 J. Alloys Compd . 374 165
[9] Liu Y, Lei B and Shi C 2005 Chem. Mater. 17 2108
[10] Trojan-Piegza J et al 2008 Chem. Mater. 20 2252
[11] Lei B et al 2007 J. Electrochem. Soc. 154 H623
[12] Cui C et al 2009 Acta Phys. Sin. 58 3565 (in Chinese)
[13] Liu B et al 2005 Chin. Phys. Lett. 22 1256
[14] Kang J and Liu Y 2006 Chin. Phys. Lett. 23 204
[15] Gasperin M 1975 Acta Crystallogr. B 31 2129
[16] Prasadarao A V et al 1991 Mater. Lett . 12 306
[17] Popp R C 1991 Luminescence and the Solid State (Amsterdam: Elsevier) p 291
[18] Qiu J et al 1999 J. Non-Cryst. Solids 244 185
[19] Clabau F et al 2005 Chem. Mater . 17 3904
[20] Jia D and Yen W M 2003 J. Electrochem. Soc. 150 H61
[21] Hosono H et al 1998 J. Phys.: Condens. Matter. 10 9541
[22] Kinoshita T et al 1999 J. Appl. Phys . 86 3729
[23] Iwasaki M et al 2003 Sci. Tech. Adv. Mater. 4 137
Related articles from Frontiers Journals
[1] XU Wei-Wei, HU Lin-Hua, LUO Xiang-Dong, LIU Pei-Sheng, DAI Song-Yuan**. The Electric Mechanism of Surface Pretreatments for Dye-Sensitized Solar Cells Based on Internal Equivalent Resistance Analysis[J]. Chin. Phys. Lett., 2012, 29(1): 047203
[2] LI Bi-Xin, CHEN Jiang-Shan, ZHAO Yong-Biao, MA Dong-Ge** . Frequency-Dependent Electrical Transport Properties of 4,4',4[J]. Chin. Phys. Lett., 2011, 28(5): 047203
[3] ZHONG Hai-Yang, LUO Xi-Xian**, MA Lu-Bin, ZHANG Ming, XING Ming-Ming, FU Yao . Preparation of Gd2O2S:Yb,Ho Phosphor via Thermolysis of Sulfur−Contained (Gd,Yb,Ho)[S2CN(C4H8)]3 Phen Complexes[J]. Chin. Phys. Lett., 2011, 28(4): 047203
[4] ZHANG Jia-Chi**, QIN Qing-Song, YU Ming-Hui, SUN Jia-Yao, SHI Liu-Rong, MA Xin-Long . Up-Conversion Photostimulated Luminescence of Mg2SnO4 for Optical Storage[J]. Chin. Phys. Lett., 2011, 28(2): 047203
[5] KANG Feng-Wen, HU Yi-Hua**, WU Hao-Yi, JU Gui-Fang . Red Afterglow Properties of Eu3+ in CaMoO4 Phosphor[J]. Chin. Phys. Lett., 2011, 28(10): 047203
[6] CUI Zhao-Feng, YUAN Shuang-Long, **, YANG Yun-Xia, Franç, ois CHEVIRE **, Franck TESSIER, CHEN Guo-Rong . Preparation and Photoluminescence Properties of Eu2+−Doped Oxyapatite-Type SrxLa10−x (SiO4)6O3−x/2[J]. Chin. Phys. Lett., 2011, 28(1): 047203
[7] DAI Peng, XU Zou-Ming, WANG Yu-Xia** . Self-Trapped Exciton Photoluminescence from Polycrystalline K2AgI3 Obtained by Solid-State Reaction Method[J]. Chin. Phys. Lett., 2011, 28(1): 047203
[8] MA Yong-Chang, ZHANG Jian-Zhu, ZHAO Jie, LIU Qing-Suo. Temperature- and Frequency-Dependent Dielectric Properties of La1.5Sr0.5NiO4-δ[J]. Chin. Phys. Lett., 2010, 27(8): 047203
[9] QIAO Xian-Feng, CHEN Jiang-Shan, MA Dong-Ge. Comparative Study on Hole Transport in N,N'-bis(naphthalen-1-yl)-N,N'- bis(pheny) Benzidine and 4,4',4''-tri(N-carbazolyl)triphenylamine[J]. Chin. Phys. Lett., 2010, 27(8): 047203
[10] WU Dong, TANG Bin, Laurent Calvez, ZHANG Xiang-Hua, ZHANG Long. Upconversion Luminescence of Er3+ Ions in Transparent Germanate Glass Ceramics Containing CaF2 Nanocrystals[J]. Chin. Phys. Lett., 2010, 27(6): 047203
[11] LIU Hong-Gang, JIN Zhi, SU Yong-Bo, WANG Xian-Tai, CHANG Hu-Dong, ZHOU Lei, LIU Xin-Yu, WU De-Xin. Extrinsic Base Surface Passivation in High Speed “Type-II'” GaAsSb/InP DHBTs Using an InGaAsP Ledge Structure[J]. Chin. Phys. Lett., 2010, 27(5): 047203
[12] LEI Bing-Fu, YUE Song, ZHANG Yong-Zhe, LIU Ying-Liang. Luminescence Properties of Sr2SnO4:Sm3+ Afterglow Phosphor[J]. Chin. Phys. Lett., 2010, 27(3): 047203
[13] CHEN Tian-Xiang, YAO Shu-De, HUA Wei, FA Tao, LI Lin, ZHOU Sheng-Qiang. Charge Transport and Magnetotransport Properties of Polyimide Irradiated by 80keV Co Ions[J]. Chin. Phys. Lett., 2009, 26(8): 047203
[14] ZHANG Hong-Jian, ZHANG Xiao-Ping, ZHAO Yong-Gang. Bipolar Resistance Switching Characteristics of ZnO/Nb-Doped SrTiO3 Heterojunctions[J]. Chin. Phys. Lett., 2009, 26(7): 047203
[15] P. Ohlckers P. Pipinys. Comment on ``Electrical Conductivity and Current-Voltage Characteristics of Individual Conducting Polymer PEDOT Nanowires''[J]. Chin. Phys. Lett., 2009, 26(5): 047203
Viewed
Full text


Abstract