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Statistics and Dynamics for the Aa-Dd Type Hydrogen Bonding System |
| WANG Hai-Jun1;HONG Xiao-Zhong1,2;BA Xin-Wu1 |
| 1Department of Chemistry, Hebei University, Baoding 071002
2School of Physical Science and Technology, Hebei University, Baoding 071002 |
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| Cite this article: |
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WANG Hai-Jun, HONG Xiao-Zhong, BA Xin-Wu 2003 Chin. Phys. Lett. 20 1158-1160 |
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Abstract The kinetics and dynamics for the growth of hydrogen bonding clusters in the Aa-Dd system are considered. The explicit relations between conversions of proton-acceptors and proton-donors and Gibbs free energy are deduced, and then the sol-gel phase transition is predicted to take place and the generalized scaling laws satisfied by the k-th moment and k-th radius near the critical point are given. The conclusions obtained from which are consistent with the statistical descriptions on the system under investigation.
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| Keywords:
82.30.Rs
35.20.Gs
82.20.Db
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Published: 01 July 2003
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| PACS: |
82.30.Rs
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(Hydrogen bonding, hydrophilic effects)
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35.20.Gs
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82.20.Db
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(Transition state theory and statistical theories of rate constants)
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