Chin. Phys. Lett.  2003, Vol. 20 Issue (7): 1155-1157    DOI:
Original Articles |
Effect of VI/II Ratio on Structure and Optoelectrical Properties of Zinc Oxide Thin Films Deposited by Metal-Organic Chemical Vapor Deposition
MA Yan;DU Guo-Tong;YANG Shu-Ren;YANG Tian-Peng;YANG Hong-Jun;YANG Xiao-Tian;ZHAO Bai-Jun;LIU Da-Li
State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130023
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MA Yan, DU Guo-Tong, YANG Shu-Ren et al  2003 Chin. Phys. Lett. 20 1155-1157
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Abstract ZnO thin films with the c-axis orientation on the (0001) sapphire substrate were grown by metal-organic chemical vapor deposition. It was demonstrated that the VI/II precursor flow-rate ratio can influence strongly on the structure and opto-electrical properties. With the increasing VI/II ratio of 130:1, the full width at half maximum of (0002) peak in x-ray diffraction is only 0.184°, the near-band-edge emission enhances remarkably and the intensity ratio of the near-band-edge emission to the deep-level emission reaches 237:1 in the photoluminescence spectrum. At the same time, the resistivity and mobility increases to 3.28 x 102Ω.cm and 25.3cm2V-1s-1. These facts indicates that the quality of the ZnO thin films could be improved by the increase of the VI/II flow rate ratio during the growth.

Keywords: 81.05.Dz      81.15.Gh      78.55.-m      73.61.-r     
Published: 01 July 2003
PACS:  81.05.Dz (II-VI semiconductors)  
  81.15.Gh (Chemical vapor deposition (including plasma-enhanced CVD, MOCVD, ALD, etc.))  
  78.55.-m (Photoluminescence, properties and materials)  
  73.61.-r (Electrical properties of specific thin films)  
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https://cpl.iphy.ac.cn/       OR      https://cpl.iphy.ac.cn/Y2003/V20/I7/01155
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MA Yan
DU Guo-Tong
YANG Shu-Ren
YANG Tian-Peng
YANG Hong-Jun
YANG Xiao-Tian
ZHAO Bai-Jun
LIU Da-Li
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