| Original Articles |
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Influence of Residual Phases on the Behaviour of Gradual Spin Transition Complexes |
| SHI Hai-Rong;YU Zhi;HUANG Hong-Bo;XIA Yuan-Fu;YOU Xiao-Zeng |
| National Laboratory of Solid State Microstructure, Department
of Physics, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
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| Cite this article: |
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SHI Hai-Rong, YU Zhi, HUANG Hong-Bo et al 2001 Chin. Phys. Lett. 18 611-613 |
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Abstract In order to interpret the large shift between the observed high spin fraction and the so-called molar high spin fraction in the Mössbauer study on gradual spin transition complexes, numerically we reveal that the effects from residual phases in the substance should be considered in the correction by Debye-Waller factors. This result shows that similar Debye-Waller factors in high and low spin states agree well with the conclusion of experimental investigations for such gradual spin transition complexes.
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| Keywords:
82.80.Ej
63.70.+h
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Published: 01 April 2001
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| PACS: |
82.80.Ej
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(X-ray, M?ssbauer, and other γ-ray spectroscopic analysis methods)
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63.70.+h
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(Statistical mechanics of lattice vibrations and displacive phase transitions)
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