Raman Scattering Study of ND4+ -Ion Motion and Structural Phase Transitions in ( ND4)2PbCl6

Chin. Phys. Lett.

1996, Vol. 13

Issue (5): 394-396 DOI:

Original Articles

Raman Scattering Study of ND₄⁺ -Ion Motion and Structural Phase Transitions in ( ND₄)₂PbCl₆

SHI Jin-rong¹;XU Yong-chen¹;Y. Kume²;R. Arnscheidt³;J. Pelzl³;WU Xiang⁴

¹Pohl Institute of Solid State Physics, Tongji University , Shanghai 200092 ²Faculty of General Education , Azabu University, Fuchinobe, Sagamihara , Kanagawa 229, Japan ³Institut für Experimentalphysk IIII, AG FestKörperspektroskopie,Ruhr-Universität Bochum , 44780 Bochum , Germany ⁴International Center for Materials Physics, Chinese Academy of Sciences, Shenyang 110015, Pohl Institute of Solid State Physics, Tongji University, Shanghai 200092

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SHI Jin-rong, XU Yong-chen, Y. Kume et al 1996 Chin. Phys. Lett. 13 394-396

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Abstract Raman spectra of the internal modes of ND₄⁺-Ion in ( ND₄)₂PbCl₆ crystal have been recorded in the temperature range of 5 - 300K. A new structural phase transition was observed at 34 K because of deuterium effect. Discontinuous behaviours of the interna1 modes of the ND₄⁺-ion at this temperature show that the structural transition is one of first order.

Keywords: 78.30.Hv 64.70.Kb

Published: 01 May 1996

PACS:	78.30.Hv	(Other nonmetallic inorganics)
	64.70.Kb

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https://cpl.iphy.ac.cn/ OR https://cpl.iphy.ac.cn/Y1996/V13/I5/0394

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	SHI Jin-rong
	XU Yong-chen
	Y. Kume
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	WU Xiang

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