We fabricate the hybrid films of colloidal CdSe/ZnS quantum dots (QDs) and poly(9-vinylcarbazole) (PVK) sandwiched between two electrodes. The voltage and temperature dependences of the electroluminescence (EL) are measured. The quantum-confined Stark effect of colloidal QDs is clearly observed. To explore the mechanism in the QD EL, hybrid films are fabricated with different concentrations of colloidal QDs. Electrons and holes are proposed to be separately transported in QDs and PVK, respectively.
We fabricate the hybrid films of colloidal CdSe/ZnS quantum dots (QDs) and poly(9-vinylcarbazole) (PVK) sandwiched between two electrodes. The voltage and temperature dependences of the electroluminescence (EL) are measured. The quantum-confined Stark effect of colloidal QDs is clearly observed. To explore the mechanism in the QD EL, hybrid films are fabricated with different concentrations of colloidal QDs. Electrons and holes are proposed to be separately transported in QDs and PVK, respectively.
WANG Zhi-Bing;ZHANG Jia-Yu;CUI Yi-Ping;YE Yong-Hong. Effect of Electrical Field on Colloidal CdSe/ZnS Quantum Dots[J]. 中国物理快报, 2008, 25(12): 4435-4438.
WANG Zhi-Bing, ZHANG Jia-Yu, CUI Yi-Ping, YE Yong-Hong. Effect of Electrical Field on Colloidal CdSe/ZnS Quantum Dots. Chin. Phys. Lett., 2008, 25(12): 4435-4438.
[1] Burroughes J H, Bradley D D C, Brown A R, Marks R N,Mackay K, Friend R H , Burns P L and Holmes A B 1990 Nature 347 539 [2] Kido J, Shionoya H and Nagai K 1995 Appl. Phys.Lett. 67 2281 [3] Furuta P, Brooks J, Thompson M E and Fr\'{echet J M J2003 J. Am. Chem. Soc. 125 13165 [4] Colvin V, Schlamp M and Alivisatos A 2002 Nature 370 354 [5] Schlamp M C, Peng X G and Alivisatos A P 1994 J.Appl. Phys. 82 5837 [6] Dabbousi B O, Rodriguez-Viejo J, Mikulec F V, Heine J R,Mattoussi H, Ober R, Jensen K F and Bawendi M G 1997 J. Phys.Chem. B 101 9463 [7] Dabbousi B O, Bawendi M G, Onitsuka O and Rubner M F 1995 Appl. Phys. Lett. 66 1316 [8] Rizzo A, Li Y, Kudera S and Sala F 2007 Appl. Phys.Lett. 90 051106 [9] Coe S, Woo W K, Bawendi M G, and Bulovic V 2002 Nature 420 800 [10] Fafard S, Raymond S, Wang G, Leon R, Leonard D,Charbonneau S, Merz J L, Petroff P M and Bowers J E 1996 Surf.Sci. 361/362 778 [11] Zhao J, Zhang J, Jiang C, Jolanta B and Thomas B 2004 J. Appl. Phys. 96 3206 [12] Miller D A B, Chemla D S, Damen T C, Gossard A C,Wiegmann W, Wood T H and Burrus C A 1984 Phys. Rev. Lett. 53 2173 [13] Wen G, Lin J and Jiang H 1995 Phys. Rev. B 525913 [14] Empedocles S A and Bawendi M G 1997 Science 278 2114 [15] Hikmet R A M, Talapin D V and Weller H 2003 J. Appl.Phys. 93 3509 [16] Taylor D 2006 IEEE Trans. Dielectric. Electron.Insul. 13 1063 [17] Angelo P D, Barra M, Cassinese A, Maglione M G, Vacca P,Minarini C and Rubino A 2007 Solid-State Electron. 51123 [18] Dunlap D 1995 Phys. Rev. B 52 939 [19] Mattoussi H, Radzilowski L, Dabbousi B O, Thomas E L,Bawendi M G and Rubner M F 1998 J. Appl. Phys. 83 7965 [20] Chan W C W 2004 Appl. Phys. Lett. 84 1925 [21] Li C, Lai H, Chen S, Suemasu T et al 2006 J. Appl.Phys. 100 023506