1Department of Microelectronics, Xi'an Jiaotong University, Xi'an 7100492Department of Electrical Engineering, Stanford University, Stanford, California 94305, USA3Department of Chemical Engineering, Stanford University, Stanford, California 94305, USA
Fermi Level Unpinning and Schottky Barrier Modification by Ti, Sc and V Incorporation at NiSi2/Si Interface
1Department of Microelectronics, Xi'an Jiaotong University, Xi'an 7100492Department of Electrical Engineering, Stanford University, Stanford, California 94305, USA3Department of Chemical Engineering, Stanford University, Stanford, California 94305, USA
摘要A new method is proposed to modify the Schottky barrier height (SBH) for nickel silicide/Si contact. Chemical and electrical properties for NiSi2/Si interface with titanium, scandium and vanadium incorporation are investigated by first-principles calculations. The metal/semiconductor interface states within the gap region are greatly decreased, which is related to the diminutions of junction leakage when Ti-cap is experimentally used in nickel silicide/Si contact process. It leads to an unpinning metal/semiconductor interface. The SBH obeys the Schottky-Mott theory. Compared to Ti substitution, the SBH for electrons is reduced for scandium and increases for vanadium.
Abstract:A new method is proposed to modify the Schottky barrier height (SBH) for nickel silicide/Si contact. Chemical and electrical properties for NiSi2/Si interface with titanium, scandium and vanadium incorporation are investigated by first-principles calculations. The metal/semiconductor interface states within the gap region are greatly decreased, which is related to the diminutions of junction leakage when Ti-cap is experimentally used in nickel silicide/Si contact process. It leads to an unpinning metal/semiconductor interface. The SBH obeys the Schottky-Mott theory. Compared to Ti substitution, the SBH for electrons is reduced for scandium and increases for vanadium.
[1] Flores F and Miranda R 1994 Adv. Mater. 6 540 [2] Tung R T 2000 Phys. Rev. Lett. 84 6078 [3] Tao M, Udeshi D, Basit N, Maldonado E and Kirk W P 2003 Appl. Phys. Lett. 82 1559 [4] Zhao Q T, Breuer U, Rije E, Lenk S and Mantl S 2005 Appl. Phys. Lett. 86 062108-1 [5] Kinoshita A, Tsuchiya Y, Yagishita A, Uchida K and Koga J2004 VLSI Symp. Tech. Dig. (Uhonolulu, Hawaii 15--17 June2004) p 168 [6] Zhang Z, Qiu Z, Liu R, \"{Ostling M and Zhang S 2007 IEEE Electron Device Lett. 28 565 [7] Yamauchi T, Nishi Y, Tsuchiya Y, Kinoshita A, Koga J andKato K 2007 IEDM Tech. Dig. (Washington, DC, USA 10--12December 2007) p 963 [8] Wong S, Chan L, Samudra G and Yeo Y C 2007 IEEEElectron Device Lett. 28 703 [9] Nishi Y, Tsuchiya Y, Kinoshita A, Yamauchi T and Koga J2007 IEDM Tech. Dig. (Washington DC, USA 10--12 December 2007)p 135 [10] Geng L, Magyari-Kope B, Zhang Z and Nishi Y 2008 IEEE Electron. Device Lett. 29 746 [11] Teodorescu V, Nistor L, Bender H, Steegen A, Lauwers A,Maex K and Van Landuyt J 2001 J. Appl. Phys. 90 167 [12] Nishimura T, Takeda J, Asami Y, Hoshino Y and Kido Y 2005 Surf. Sci. 588 71 [13] Hou T, Lei T and Chao T 1999 IEEE Electron. DeviceLett. 20 572 [14] Lee T L, Lee M Z, Lei T F and Lee C L 2005 J.Electrochem. Soc. 152 G158 [15] Atomistix ToolKit Manual, Atomistix, Copenhagen, Denmark. [Online]. Available: http://www.atomistix.com/ manuals/ATK{\_2.3/ [16] Kresse G and Hafner J 1993 Phys. Rev. B 47558