CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES |
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Synthesis and Characterization of Alkaline-Earth Metal (Ca, Sr, and Ba) Doped Nanodimensional LaMnO3 Rare-Earth Manganites |
Asma Khalid1, Saadat Anwar Siddiqi2**, Affia Aslam3 |
1School of Physics, University of Melbourne, Parkville VIC 3010, Australia 2Interdisciplinary Research Centre in Biomedical Materials, COMSATS Institute of Information Technology, Defence Road, Off Raiwind Road, Lahore-54700, Pakistan 3Department of Physics, University of Hail, Hail-30055, Saudi Arabia
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Cite this article: |
Asma Khalid, Saadat Anwar Siddiqi, Affia Aslam 2013 Chin. Phys. Lett. 30 077501 |
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Abstract The substitution of divalent cations of alkaline-earth elements in nanodimensional structures of rare-earth manganites produces advanced materials with potential electrical and magnetic functionalities. A systematic investigation of La0.65A0.35MnO3 (A = Ca, Sr, Ba) materials synthesized with a modified citrate route adopting ethanol dehydration has been undertaken. The structural and morphological analyses are carried out by using x-ray diffraction and scanning electron microscopy, respectively. Resistivity measurements are performed in variation with temperature to study the electrical transport properties which are found to vary with the size of the A-site cationic radius. Room temperature magnetic measurements are carried out to investigate the type of magnetic phase present in materials. The stability of the magnetic phase and coercivity are found to be dependent on the size of nanocrystallites.
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Received: 04 February 2013
Published: 21 November 2013
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