| ATOMIC AND MOLECULAR PHYSICS |
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Direct Observation on H-Elimination Enhancement from C$_{2}$H$_{4}$ through Non-Adiabatic Process by Femtosecond Laser Induced Coulomb Explosion |
| Wuwei Jin1,2, Chuncheng Wang1,2*, Xiaoge Zhao1,2, Yizhang Yang1,2, Dianxiang Ren1,2, Zejin Liu1,2, Xiaokai Li1,2, Sizuo Luo1,2, and Dajun Ding1,2* |
1Institute of Atomic and Molecular Physics, Jilin University, Changchun 130012, China
2Jilin Provincial Key Laboratory of Applied Atomic and Molecular Spectroscopy, Jilin University, Changchun 130012, China
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Wuwei Jin, Chuncheng Wang, Xiaoge Zhao et al 2024 Chin. Phys. Lett. 41 053101 |
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Abstract Ethylene, the simplest model of a carbon-carbon double bond system, is pivotal in numerous chemical and biological processes. By employing intense infrared laser pump-probe techniques alongside coincidence measurements, we investigate the ultrafast non-adiabatic dynamics involved in the breakage of carbon-carbon double bonds and hydrogen elimination in dissociation of ethylene. Our study entails analyzing the dynamic kinetic energy release spectra to assess three bond-breaking scenarios, movements of nuclei, and structural changes around the carbon atoms. This allows us to evaluate the relaxation dynamics and characteristics of various dissociative states. Notably, we observe a significant rise in the yield of fragments resulting from C–H bond breakage with the delay time extended, suggesting non-adiabatic coupling through conical intersections from C–C bond breakage as a probable cause.
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Received: 28 February 2024
Published: 28 May 2024
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| PACS: |
32.80.-t
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(Photoionization and excitation)
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32.80.Fb
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(Photoionization of atoms and ions)
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33.80.Eh
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(Autoionization, photoionization, and photodetachment)
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