CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES |
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Ultrafast Photophysics of Star-Like Molecules with Benzene and Triazine Core |
FENG Wen-Ke1, KONG Sheng1, XIAO Li-Xin1, MENG Kang1, WANG Shu-Feng1, GONG Qi-Huang1 |
State Key Laboratory for Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 |
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Cite this article: |
FENG Wen-Ke, KONG Sheng, XIAO Li-Xin et al 2009 Chin. Phys. Lett. 26 127801 |
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Abstract Static and transient spectroscopic characters of newly synthesized start-like molecules, 1,3,5-tri(10-butyl-3-propenyl-10H-phenothiazine)-benzene (TP3B) and 2,4,6-tri(10-butyl-3-propenyl -10H-phenothiazine)-[1,3,5]triazine (TP3T), are studied using static, picosecond fluorescence and femtosecond transient absorption spectroscopy. The results show that when the benzene group is in the center, a large conjugation system is formed, while a fast electron-transfer process happens when the center group is triazine.
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Keywords:
78.40.Me
78.47.Cd
78.47.jc
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Received: 02 September 2009
Published: 27 November 2009
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[1] Qu B, Chen Z J, Xu F, Cao H Y, Huang M M and Gong Q H 2006 Mater. Lett. 60 1927 [2] Qu B, Chen Z J, Xu F, Cao H Y, Lan Z H, Wang Z Y and GongQ H 2007 Org. Electron. 8 529 [3] Yang Y, Zhou Y, He Q G, He C, Yang C H, Bai F L and Li Y F2009 J. Phys. Chem. B 113 7745 [4] Goodson T G I$\!$I$\!$I 2005 Acc. Chem. Res. 38 99 [5] Ramakrishna G, Bhaskar A and Goodson T G I$\!$I$\!$I 2006 J. Phys. Chem. B 110 20872 [6] Bhaskar A, Ramakrishna G, Twieg R J and Goodson T GI$\!$I$\!$I 2007 J. Phys. Chem. C 111 14607 [7] Varnavski O P, Ostrowski J C, Sukhomlinova L, Twieg R J,Bazan G C, and Goodson T G I$\!$I$\!$I 2002 J. Am. Chem. Soc. 124 1736 [8] Krummacher B C, Choong V, Mathai M K, Choulis S A, So F,Jermann F, Fiedler T and Zachau M 2006 Appl. Phys. Lett. 88 113506 [9] Wang M L, Liu J Z and Xu C X 2006 Chin. Phys.Lett. 23 3088 [10] Li M T, Li W L, Chen L L, Kong Z G, Chu B, Li B, Hu Z Zand Zhang Z Q 2006 Appl. Phys. Lett. 88 091108 [11] Tong K Q, Xu C X, Wang Q, Gu B X, Zheng K, Ye L H and LiX S 2008 Chin. Phys. Lett. 25 4453 [12] Zeng Q, Liu Y L, Meng K, Zhao X J, Wang S F and Gong Q H2009 Chin. Phys. Lett. 26 077810 [13] Tu G L, Mei C Y, Zhou Q G, Cheng Y X, Geng Y H, Wang L X,Ma D G, Jing X B and Wang F S 2006 Adv. Funct. Mater. 16101 [14] Ramakrishna G and Goodson T I$\!$I$\!$I 2007 J.Phys. Chem. A 111 993 [15] Bhaskar A, Ramakrishna G, Lu Z K, Twieg R, Hales J M,Hagan D J, Stryland E V and Goodson T 2006 J. Am. Chem. Soc. 128 11840 [16] Zhang X H, Choi S H, Choi D H and Ahn K H 2005 Tetrahedron. Lett. 46 5273 [17] Stockmann A, Kurzawa J, Fritz N, Acar N, Schneider S,Daub J, Engl R and Clark T 2002 J. Phys. Chem. A 1067958 [18] Acar N, Kurzawa J, Fritz N, Stockmann A, Roman C,Schneider S and Clark T 2003 J. Phys. Chem. A 107 9530 [19] Cho D W, Fujitsuka M, Sugimoto A, Yoon U C, Mariano P Sand Majima T 2006 J. Phys. Chem. B 110 11062 [20] Suneesh C V and Gopidas K R, 2009 J. Phys. Chem. C 113 1606 |
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