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Fluorescence Enhancement Ratio Dropdown at Low Fluences during Femtosecond Double Pulse Laser Ablation |
Sima SINGHA2, Robert J. GORDON2, HU Zhan1 |
1Institute of Atomic and Molecular Physics, Jilin University, Changchun 1300212Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60607-7061, USA |
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Cite this article: |
Sima SINGHA, Robert J. GORDON, HU Zhan 2008 Chin. Phys. Lett. 25 2653-2656 |
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Abstract In the study of double pulse ablation of materials (silicon and copper), a dropdown of double pulse to single pulse fluorescence signal enhancement at low fluences is observed. The dropdown is analysed with a simple theoretical one-dimensional heat diffusion model and verified by fluorescence time constants change as a function of fluence. The dropdown is explained as a result of liquid-solid mixture layer at the liquid and solid boundary. The effect of the layer becomes important at low fluences.
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Keywords:
78.70.-g
52.5.Rv
66.10.Cb
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Received: 24 December 2007
Published: 26 June 2008
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