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Mn Nanowhiskers of a Novel Hexagonal Phase Grown from Hydrogen Activated Laves Phase Alloys |
WU Er-Dong, GUO Xiu-Mei |
Shenyang National Laboratory for Material Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 |
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Cite this article: |
WU Er-Dong, GUO Xiu-Mei 2008 Chin. Phys. Lett. 25 2607-2609 |
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Abstract With the aid of hydrogenation/dehydrogenation, nanorod whiskers of transition metal Mn can grow spontaneously from Zr1-xTixMnCr Laves phase alloys at room temperature. The finding introduces a distinguishingly different element into metal whisker family, and provides a potential technique for fabrication of one-dimensional metal nanostructures. Moreover, it is found that the segregated Mn in whiskers forms a novel hexagonal structure, which partially fulfills the long predicted allotropic form and adds more complexity to the structures of Mn.
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Keywords:
68.70.+w
61.46.Km
61.66.Bi
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Received: 29 January 2008
Published: 26 June 2008
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PACS: |
68.70.+w
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(Whiskers and dendrites (growth, structure, and nonelectronic properties))
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61.46.Km
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(Structure of nanowires and nanorods (long, free or loosely attached, quantum wires and quantum rods, but not gate-isolated embedded quantum wires))
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61.66.Bi
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(Elemental solids)
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[1] Sinha V K, Pourarian F and Wallace W E 1982 J. Alloys Compd. 87 283 [2] Liu B H, Kim D K, Lee K Y and Lee J Y 1996 J. Alloys Compd. 240 214 [3] Huang T Z, Wu Z, Yu X B, Chen J Z, Xia B J, Huang T S and Xu N X2004 Intermetallics 12 91 [4] Guo X M and Wu E 2008 J. Alloys Compd. 455 191 [5] Galyon G T 2004 A History of Tin Whisker Theory: 1946to 2004. 2004 SMTA Int. Conf. Proc. (Chicago, IL) 26-30 696 [6] Arnold S M 1956 Tech. Proc. 43rd Annual Conv. Am. Electropl.Soc. p 26 [7] Barsoum M W, Hoffman E N, Doherty R D, Gupta S and Zavaliangos A2004 Phys. Rev. Lett. 93 206104 [8] Cheng Y T, Weiner A M, Wong C A, Balogh M P and Lukitsch M J 2002 Appl. Phys. Lett. 81 3248 [9] Sun Z M and Barsoum M W 2005 J. Mater. Res. 20 1087 [10] Barsoum M W and Farber L 1999 Science 284 937 [11] Ross R B 1992 Metallic Materials Specification Handbook4th edn (London: Chapman) [12] Hobbs D, Hafner J and Spi\v s\'ak D 2003 Phys. Rev. B 68 014407 [13] Oberteuffer J A and Ibers J A 1970 Acta Cryst. B 261499 [14] Asada T and Terakura K 1993 Phys. Rev. B 47 15992 [15] Hujihisa H and Takemura K 1995 Phys. Rev. B 52 13257 [16] Zheng-Johansson J X, Eriksson O, Johansson B, Fast L and Ahuja R1998 Phys. Rev. B 57 10989 [17] Pauling L 1960 The Nature of the Chemical Bond (New York:Cornell University) [18] G\"unzel E and Schubert K 1958 Z. Metallkd. 49 124 [19] Tolbert S H, Herhold A B, Brus L E and Alivisatos A P 1996 Phys. Rev. Lett. 76 4384 [20] Sun S and Murray C B 1999 J. Appl. Phys. 85 4325 [21] Xia Y, Yang P, Sun Y, Wu Y, Mayers B, Gates B, Yin Y, Kim F andYan H 2003 Adv. Mater. 15 353 [22] Puntes V F, Krishnan K M and Alivisatos A P 2001 Science 291 2115 |
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