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Four-State Model for Three-Branch Molecule’s Two-Photon Absorption Properties |
SU Yan;WANG Pei-Ji;ZHAO Peng;RONG Zhen-Yu |
School of Science, Jinan University, Jinan 250022 |
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Cite this article: |
SU Yan, WANG Pei-Ji, ZHAO Peng et al 2006 Chin. Phys. Lett. 23 1154-1156 |
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Abstract We present a four-state model for calculating the two-photon absorption of multi-branched molecules by using the time-depended function method. The numerical results indicate that the two-photon absorption cross section has a strong enhancement for three-branch molecules compared to two-branch structures. The maximal two-photon-absorption cross section is 2.358×10-47cm4s/photon. At the same time, the charge-transfer process for the charge-transfer states is visualized in order to explain mechanism about the maximal TPA cross section.
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Keywords:
33.15.Kr
31.15.Ar
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Published: 01 May 2006
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PACS: |
33.15.Kr
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(Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility)
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31.15.Ar
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