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Band (5, 0) in the Red System A2II1 - X2Σ+ of CN Studied by Optical Heterodyne Magnetic Rotation Enhanced Concentration Modulation Spectroscopy |
XU Chao-Xiong1;WU Ling2;LIU Jin-Jun1;WU Sheng-Hai1;DUAN Chuan-Xi2;CHEN Yang-Qin1;LIU Yu-Yu1,2,3 |
1Key Laboratory of Optical and Magnetic Resonance
Spectroscopy and Department of Physics, East China Normal University, Shanghai 200062
2Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071
3Department of Physics, Huazhong Normal University, Wuhan 430079 |
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Cite this article: |
XU Chao-Xiong, WU Ling, LIU Jin-Jun et al 2002 Chin. Phys. Lett. 19 1277-1279 |
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Abstract We study the CN radical using optical heterodyne magnetic rotation enhanced concentration modulation spectroscopy in the visible region. The radical has been produced in the ac glow discharge of acetonitrile with helium as the carrier gas. The (5, 0) band of the red system A2II1 - X2Σ+ in the range 17450--17830cm-1 has been observed and rotationally analysed. We determine a set of precise molecular constants for the v = 5 vibrational level of CN in the A2II1 state.
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Keywords:
33.20.-t
42.62.Fi
33.15.Mt
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Published: 01 September 2002
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PACS: |
33.20.-t
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(Molecular spectra)
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42.62.Fi
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(Laser spectroscopy)
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33.15.Mt
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(Rotation, vibration, and vibration-rotation constants)
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