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Self-Organization of CdS Nanoparticles in Polystyrene Film |
LIANG Hai-Chun1;XIANG Hong2;RONG Min-Zhi1;ZHANG Ming-Qiu1;ZENG Han-Min1;WANG Shu-Feng2;GONG Qi-Huang2 |
1Materials Science Institute, Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, Zhongshan University, Guangzhou 510275
2State Key Laboratory for Mesophysics, Peking University, Beijing 100871
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Cite this article: |
LIANG Hai-Chun, XIANG Hong, RONG Min-Zhi et al 2002 Chin. Phys. Lett. 19 871-874 |
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Abstract Self-organization of nano-CdS particles in polystyrene can be observed by encapsulating the particles with n-dodecyl mercaptan owing to a strong electron transfer interaction between the modified CdS nanoparticles and aliphatic carbons in polystyrene. Consequently, ultraviolet/visible absorption edge of the treated nano-CdS/polystyrene composites is further blue-shifted in addition to the shift caused by quantum size effect, and the fluorescence emission peak of the composite becomes red-shifted and narrow.
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Keywords:
81.05.Dz
82.80.Ch
85.40.Ux
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Published: 01 June 2002
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