Chin. Phys. Lett.  2000, Vol. 17 Issue (12): 896-898    DOI:
Original Articles |
BO2-F+ Centers in the Radiation-damaged YCOB Crystals
RUAN Yong-Feng1;Hiroshi NAKAO2;Takatomo SASAKI2
1Department of Physics, Tianjin University, Tianjin 300072 2Department of Electrical Engineering, Osaka University, Osaka 565-0871, Japan
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RUAN Yong-Feng, Hiroshi NAKAO, Takatomo SASAKI 2000 Chin. Phys. Lett. 17 896-898
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Abstract An intense paramagnetic EPR signal generated from x-ray-irradiated, powdered YCOB crystals was observed at the liquid nitrogen temperature for the first time. Five peaks, located at the positions where the effective g factor equals to 1.992, 1.986, 1.980, 1.974 and 1.965, labeled as A, B, C, D and E respectively, were observed. It is believed that the peaks A, B, C and D generated from the BO2-F+ center which is a single electron trapped in an oxygen vacancy which was originally occupied by an O2- ion bonded to a (BO3)3- anion group. The peak E is thought of coming from Y2+ ions that are formed by the Y3+ ions trapping electrons. The mechanism for the formation of the radiation-induced defects in the YCOB crystals is suggested.
Keywords: 61.80.Az      61.72.Hh      42.70.Mp     
Published: 01 December 2000
PACS:  61.80.Az (Theory and models of radiation effects)  
  61.72.Hh (Indirect evidence of dislocations and other defects (resistivity, slip, creep, strains, internal friction, EPR, NMR, etc.))  
  42.70.Mp (Nonlinear optical crystals)  
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