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Relationship Between Superconducting Transition Temperature and Combinative Energy in YBa2Cu3O7-δ |
CHENG Li-li;DU Xu;QIN Xiao-chuan;ZHANG Han |
Materials Physics Laboratory, State Key Laboratory for Artificial Microstructure and Mesoscope Physics, Department of Physics, Peking University, Beijing 100871 |
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Cite this article: |
CHENG Li-li, DU Xu, QIN Xiao-chuan et al 1999 Chin. Phys. Lett. 16 446-448 |
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Abstract Separating the unit cell of YBa2Cu3O7-δ into perovskite and rock salt blocks and considering the interaction between the two blocks, a computer program has been developed to calculate the interaction called combinative energy, between the blocks. The combinative energy in YBa2Cu3O7-δ with different 6 value from 0.07 to 0.62 has been calculated. A close relationship between the superconducting transition temperature and the combinative energy in YBa2Cu3O7-δ has been established, and the change of the combinative energy found to be closely related to the transformation from orthorhombic I to II. It is believed that the interaction between the two blocks in the unit cell is of great importance to the superconductivity in YBa2Cu3O7-δ.
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Keywords:
74.25.-q
74.80.-g
74.80. Dm
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Published: 01 June 1999
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