An Analytical Expression of Magic Angle Spinning Nuclear Magnetic Resonance Free Induction Decay in Two-Site Exchange Problem

Chin. Phys. Lett.

1998, Vol. 15

Issue (6): 453-454 DOI:

Original Articles

An Analytical Expression of Magic Angle Spinning Nuclear Magnetic Resonance Free Induction Decay in Two-Site Exchange Problem

SHEN Yi-min^1,2;KAJI Hironori²;HORII Fumitaka²

Analytical Center, Fudan University, Shanghai 200433 ²Institute for Chemical Research, Kyoto University, Uji, Kyoto 611, Japan

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SHEN Yi-min, KAJI Hironori, HORII Fumitaka 1998 Chin. Phys. Lett. 15 453-454

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Abstract An analytical expression of free induction decay has been derived for calculating the magic angle spinning sideband patterns of nuclear magnetic resonance spectra in a two-site exchange problem. The expression has been confirmed by comparing the calculated spinning sideband patterns for powdered crystalline dimethyl sulfone at different exchange rates with experimentally measured spectra at various temperatures.

Keywords: 76.60.-k 33.25.-j

Published: 01 June 1998

PACS:	76.60.-k	(Nuclear magnetic resonance and relaxation)
	33.25.-j

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https://cpl.iphy.ac.cn/ OR https://cpl.iphy.ac.cn/Y1998/V15/I6/0453

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