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Phonon Characterization of Raman Spectra in High Tc
Superconductors Y1-xGdxBa2Cu3O7-δ
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ZHANG Mingsheng (ZHANG Ming-sheng);CHEN Qiang;JIN Xin*;YIN Zhen*;YAO Xixian* |
Center for Materials Analysis, National Laboratory of Solid State Microstructures, and
*Department of Physics, Nanjing University, Nanjing 210008
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Cite this article: |
ZHANG Mingsheng (ZHANG Ming-sheng), CHEN Qiang, JIN Xin et al 1994 Chin. Phys. Lett. 11 31-34 |
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Abstract Concentration-dependent Raman spectra of Y1-xGdxBa2Cu3O7-δ(x=0.4, 0.6, 0.8 and 1.0) show that the Raman mode from O(4) bridging shifts upward due to the increased symmetry of crystal potential. The linewidth and intensity of 508cm-1 mode are decreased and increased with increasing x, respectively which is attributed to the charge transfer from the CuO basal planes to the CuO2 planes. Two second-order Raman modes at 798 and 896cm-1 have been observed and confirmed.
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Keywords:
63.20.Dj
78.30.Er
74.30.-e
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Published: 01 January 1994
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