| ATOMIC AND MOLECULAR PHYSICS |
|
|
|
|
Pressure-Induced Distinct Self-Trapped Exciton Emission in Sb$^{3+}$-Doped Cs$_{2}$NaInCl$_{6}$ Double Perovskite |
| Youjia Feng1†, Yaping Chen1†, Leyao Wang1, Jiaxiang Wang1, Duanhua Chang1, Yifang Yuan1, Min Wu2, Ruijing Fu3, Lili Zhang1*, Qinglin Wang2*, Kai Wang2, Haizhong Guo1, and Lingrui Wang1* |
1Key Laboratory of Materials Physics (Ministry of Education), School of Physics, Zhengzhou University, Zhengzhou 450001, China
2Shandong Key Laboratory of Optical Communication Science and Technology, School of Physics Science and Information Technology, Liaocheng University, Liaocheng 252059, China
3College of Applied Physics and Materials, Wuyi University, Jiangmen 529020, China
|
|
| Cite this article: |
|
Youjia Feng, Yaping Chen, Leyao Wang et al 2024 Chin. Phys. Lett. 41 063201 |
|
|
|
|
Abstract The Cs$_{2}$NaInCl$_{6}$ double perovskite is one of the most promising lead-free perovskites due to its exceptional stability and straightforward synthesis. However, it faces challenges related to inefficient photoluminescence. Doping and high pressure are employed to tailor the optical properties of Cs$_{2}$NaInCl$_{6}$. Herein, Sb$^{3+}$ doped Cs$_{2}$NaInCl$_{6}$ (Sb$^{3+}$:Cs$_{2}$NaInCl$_{6})$ was synthesized and it exhibits blue emission with a photoluminescence quantum yield of up to 37.3%. Further, by employing pressure tuning, a blue stable emission under a very wide range from 2.7 GPa to 9.8 GPa is realized in Sb$^{3+}$:Cs$_{2}$NaInCl$_{6}$. Subsequently, the emission intensity of Sb$^{3+}$:Cs$_{2}$NaInCl$_{6}$ experiences a significant increase (3.3 times) at 19.0 GPa. It is revealed that the pressure-induced distinct emissions can be attributed to the carrier self-trapping and detrapping between Cs$_{2}$NaInCl$_{6}$ and Sb$^{3+}$. Notably, the lattice compression in the cubic phase inevitably modifies the band gap of Sb$^{3+}$:Cs$_{2}$NaInCl$_{6}$. Our findings provide valuable insights into effects of the high pressure in further boosting unique emission characteristics but also offer promising opportunities for development of doped double perovskites with enhanced optical functionalities.
|
|
|
Received: 27 March 2024
Published: 20 June 2024
|
|
| PACS: |
32.30.Jc
|
(Visible and ultraviolet spectra)
|
| |
32.30.Rj
|
(X-ray spectra)
|
| |
32.50.+d
|
(Fluorescence, phosphorescence (including quenching))
|
|
|
|
|
|
| [1] | Chen A, Jing X L, Wang T Y, Zhao T T, Zhang Y, Zhou D L, Sun R, Zhang X T, Liu R, Liu B, Li Q J, and Liu B B 2022 Inorg. Chem. 61 6488 |
| [2] | Zhao X G, Yang D W, Ren J C, Sun Y H, Xiao Z W, and Zhang L J 2018 Joule 2 1662 |
| [3] | Igbari F, Wang Z K, and Liao L S 2019 Adv. Energy Mater. 9 1803150 |
| [4] | Maughan A E, Ganose A M, Scanlon D O, and Neilson J R 2019 Chem. Mater. 31 1184 |
| [5] | Bibi A, Lee I, Nah Y, Allam O, Kim H, Quan L N, Tang J, Walsh A, Jang S S, Sargent E H, and Kim D H 2021 Mater. Today 49 123 |
| [6] | Wolf N R, Connor B A, Slavney A H, and Karunadasa H I 2021 Angew. Chem. Int. Ed. 60 16264 |
| [7] | Zeng R S, Zhang L L, Xue Y, Ke B, Zhao Z, Huang D, Wei Q L, Zhou W C, and Zou B S 2020 J. Phys. Chem. Lett. 11 2053 |
| [8] | Arfin H, Kshirsagar A S, Kaur J, Mondal B, Xia Z, Chakraborty S, and Nag A 2020 Chem. Mater. 32 10255 |
| [9] | Liu X Y, Xu X, Li B, Yang L L, Li Q, Jiang H, and Xu D S 2020 Small 16 2002547 |
| [10] | Noculak A, Morad V, McCall K M, Yakunin S, Shynkarenko Y, Wörle M, and Kovalenko M V 2020 Chem. Mater. 32 5118 |
| [11] | Ahmad R, Zdražil L, Kalytchuk S, Naldoni A, Rogach A L, Schmuki P, Zboril R, and Kment Š 2021 ACS Appl. Mater. & Interfaces 13 47845 |
| [12] | Zhou B, Liu Z X, Fang S F, Zhong H Z, Tian B B, Wang Y, Li H N, Hu H L, and Shi Y M 2021 ACS Energy Lett. 6 3343 |
| [13] | Zhu D X, Zaffalon M L, Zito J, Cova F, Meinardi F, De Trizio L, Infante I, Brovelli S, and Manna L 2021 ACS Energy Lett. 6 2283 |
| [14] | Saikia S, Joshi A, Arfin H, Badola S, Saha S, and Nag A 2022 Angew. Chem. Int. Ed. 61 e202201628 |
| [15] | Zhou B, Liu Z X, Fang S F, Nie J H, Zhong H Z, Hu H L, Li H N, and Shi Y M 2022 J. Phys. Chem. Lett. 13 9140 |
| [16] | Jiang F, Wu Z N, Lu M, Gao Y B, Li X, Bai X, Ji Y, and Zhang Y 2023 Adv. Mater. 35 2211088 |
| [17] | Jing Y Y, Liu Y, Zhao J, and Xia Z G 2019 J. Phys. Chem. Lett. 10 7439 |
| [18] | Jing X L, Zhou D L, Sun R, Zhang Y, Li Y C, Li X D, Li Q J, Song H W, and Liu B B 2021 Adv. Funct. Mater. 31 2100930 |
| [19] | Shi Y, Zhao W Y, Ma Z W, Xiao G J, and Zou B 2021 Chem. Sci. 12 14711 |
| [20] | Liao Q H, Meng Q, Jing L, Pang J M, Pang Q, and Zhang J Z 2021 J. Phys. Chem. C 125 18372 |
| [21] | Zhang L, Liu Z T, Sun X N, Niu G M, Jiang J T, Fang Y Y, Duan D F, Wang K, Sui L Z, Yuan K J, Wu G R, and Zou B 2022 Adv. Opt. Mater. 10 2101892 |
| [22] | Schettino V and Bini R 2003 Phys. Chem. Chem. Phys. 5 1951 |
| [23] | Chen B, Lin J F, Chen J H, Zhang H Z, and Zeng Q S 2016 MRS Bull. 41 473 |
| [24] | Mao H K, Chen B, Chen J H, Li K, Lin J F, Yang W G, and Zheng H Y 2016 Matter Radiat. Extremes 1 59 |
| [25] | Zhang L J, Wang Y C, Lv J, and Ma Y M 2017 Nat. Rev. Mater. 2 17005 |
| [26] | Gao F F, Qin Y, Li Z G, Li W, Hao J, Li X, Liu Y G, Howard C J, Wu X, Jiang X X, Lin Z S, Lu P X, and Bu X H 2024 ACS Nano 18 3251 |
| [27] | Zhao D L, Cong M, Liu Z, Ma Z W, Wang K, Xiao G J, and Zou B 2023 Cell Rep. Phys. Sci. 4 101445 |
| [28] | Yang H J, Shi W W, Nagaoka Y, Liu Z X, Li R P, and Chen O 2023 J. Phys. Chem. C 127 2407 |
| [29] | Zhang J, Li M X, Wang D H, Chu B H, Zhang S F, Xu Q F, and Wang K 2023 J. Mater. Chem. A 11 19427 |
| [30] | Zhao W Y, Ma Z W, Shi Y, Fu R J, Wang K, Sui Y M, Xiao G J, and Zou B 2023 Cell Rep. Phys. Sci. 4 101663 |
| [31] | Fang Y Y, Zhang L, Yu Y S, Yang X Y, Wang K, and Zou B 2021 CCS Chem. 3 2203 |
| [32] | Guo S H, Zhao Y S, Bu K J, Fu Y P, Luo H, Chen M T, Hautzinger M P, Wang Y Q, Jin S, Yang W G, and Lü X J 2020 Angew. Chem. Int. Ed. 59 17533 |
| [33] | Liang Y F, Wu M, Tian C, Huang X L, Huang Y P, Lekina Y, Shen Z X, and Yang X Y 2021 ACS Appl. Energy Mater. 4 10003 |
| [34] | Guo S H, Bu K J, Li J W, Hu Q Y, Luo H, He Y H, Wu Y H, Zhang D Z, Zhao Y S, Yang W G, Kanatzidis M G, and Lü X J 2021 J. Am. Chem. Soc. 143 2545 |
| [35] | Geng T, Wei S, Zhao W Y, Ma Z W, Fu R J, Xiao G J, and Zou B 2021 Inorg. Chem. Front. 8 1410 |
| [36] | Wang J X, Wang L R, Wang F, Jiang S, and Guo H Z 2021 Phys. Chem. Chem. Phys. 23 19308 |
| [37] | Jaffe A, Lin Y, Mao W L, and Karunadasa H I 2017 J. Am. Chem. Soc. 139 4330 |
| [38] | Zhang L, Liu C M, Wang L R, Liu C L, Wang K, and Zou B 2018 Angew. Chem. Int. Ed. 57 11213 |
| [39] | Wu L W, Dong Z Y, Zhang L, Liu C L, Wang K, and Zou B 2019 ChemSusChem 12 3971 |
| [40] | Wang J X, Wang L R, Li Y Q, Fu R J, Feng Y J, Chang D H, Yuan Y F, Gao H, Jiang S, Wang F, Guo E J, Cheng J G, Wang K, Guo H Z, and Zou B 2022 Adv. Sci. 9 2203442 |
| [41] | Li Q, Wang Y G, Pan W C, Yang W G, Zou B, Tang J, and Quan Z W 2017 Angew. Chem. Int. Ed. 56 15969 |
| [42] | Wang L R, Yao P P, Wang F, Li S F, Chen Y P, Xia T Y, Guo E J, Wang K, Zou B, and Guo H Z 2020 Adv. Sci. 7 1902900 |
| [43] | Ma Z W, Li F F, Sui L Z, Shi Y, Fu R J, Yuan K J, Xiao G J, and Zou B 2020 Adv. Opt. Mater. 8 2000713 |
| [44] | Zhang L, Li S X, Sun H Y, Jiang Q W, Wang Y, Fang Y Y, Shi Y, Duan D F, Wang K, Jiang H, Sui L Z, Wu G R, Yuan K J, and Zou B 2023 Angew. Chem. Int. Ed. 62 e202301573 |
| [45] | Yuan Y F, Zhu X D, Zhou Y H, Chen X L, An C, Zhou Y, Zhang R R, Gu C C, Zhang L L, Li X J, and Yang Z R 2021 NPG Asia Mater. 13 15 |
| [46] | Schmidt T, Lischka K, and Zulehner W 1992 Phys. Rev. B 45 8989 |
| [47] | Fang Y Y, Zhang L, Wu L W, Yan J J, Lin Y, Wang K, Mao W L, and Zou B 2019 Angew. Chem. Int. Ed. 58 15249 |
| [48] | Zhang L, Wu L W, Wang K, and Zou B 2019 Adv. Sci. 6 1801628 |
| [49] | de Jong M, Seijo L, Meijerink A, and Rabouw F T 2015 Phys. Chem. Chem. Phys. 17 16959 |
| [50] | Wang J X, Yuan Y F, Liu C L, Fu R J, Wang L R, Zhang F, Ma L, Jiang S, Shi Z F, and Guo H Z 2023 Phys. Rev. B 107 214111 |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
