Capacitance of Organic Schottky Diodes Based on Copper Phthalocyanine (CuPc)
LI Zhong-Liang, WU Zhao-Xin, JIAO Bo, MAO Gui-Lin, HOU Xun
Key Laboratory of Photonics Technology for Information (Shaanxi Province), and Key Laboratory for Physical Electronics and Devices of the Ministry of Education, School of Electronic and Information Engineering, Xi'an Jiaotong University, Xi'an 710049
Capacitance of Organic Schottky Diodes Based on Copper Phthalocyanine (CuPc)
LI Zhong-Liang, WU Zhao-Xin, JIAO Bo, MAO Gui-Lin, HOU Xun
Key Laboratory of Photonics Technology for Information (Shaanxi Province), and Key Laboratory for Physical Electronics and Devices of the Ministry of Education, School of Electronic and Information Engineering, Xi'an Jiaotong University, Xi'an 710049
The capacitance of an organic Schottky diode based on copper phthalocyanine (CuPc) is investigated. Based on the organic small-signal equivalent model established, we calculate the reverse capacitance CMetal of the organic Schottky diode with different kinds of metal cathodes (Mg, Al, Au). It is found that the reverse capacitance of the organic Schottky diode shows behavior as C Mg >C Al >C Au at the same frequency, and according to our analysis, the reverse Schottky junction capacitance Cj is expected to have little effect on the reverse capacitance of the organic Schottky diode, and the space-charge limited current capacitance CS is considered to dominate the reverse capacitance, which limits the improvement of frequency characteristics of organic Schottky diodes.
The capacitance of an organic Schottky diode based on copper phthalocyanine (CuPc) is investigated. Based on the organic small-signal equivalent model established, we calculate the reverse capacitance CMetal of the organic Schottky diode with different kinds of metal cathodes (Mg, Al, Au). It is found that the reverse capacitance of the organic Schottky diode shows behavior as C Mg >C Al >C Au at the same frequency, and according to our analysis, the reverse Schottky junction capacitance Cj is expected to have little effect on the reverse capacitance of the organic Schottky diode, and the space-charge limited current capacitance CS is considered to dominate the reverse capacitance, which limits the improvement of frequency characteristics of organic Schottky diodes.
[1] Myny K, Steudel S, Vicca P et al 2008 Appl. Phys. Lett. 93 9 [2] Baude P F, Ender D A, Haase M A et al 2003 Appl. Phys. Lett. 82 22 [3] Cantatore E, Geuns T C T, Gelinck G H et al 2006 Proceeding of the IEEE International Solid-State Circuit Conference (ISSCC) (San Francisco, CA 5-9 February 2006) p 84 [4] Gelinck G H, Huitema H E A, Van Veenendaal E et al 2004 Nature Mater. 3 2 [5] Someya T, Kato Y, Sekitani T et al 2005 Proc. Natl. Acad. Sci. U.S.A. 102 35 [6] Subramanian V, Frechet J M J, Chang P C et al 2005 Proc. IEEE 93 7 [7] Wang H, Li C H, Pan F, Wang H B and Yan D H 2009 Chin. Phys. Lett. 26 118501 [8] Cupta R K and Singh R A 2004 Mater. Sci. Semiconduct. Proc. 7 1 [9] Pal B N, Sun J, Jung B J et al 2008 Adv. Mater. 20 5 [10] Ma L, Ouyang J and Yang Y 2004 Appl. Phys. Lett. 84 4786 [11] Huang C Y, Lin S Y, Cheng S S et al 2007 J. Vacuum Sci. Technol. B: Microelectronics and Nanometer Structures 25 1 [12] Ai Y, Gowrisanker S, Jia H et al 2007 Appl. Phys. Lett. 90 26 [13] Anthopoulos T D and Shafai T S 2000 Phys. Status Solidi A 181 2 [14] Gupta R K and Singh R A 2005 J. Mater. Sci. Mater. Electron. 16 5 [15] Saxena V and Santhanam K S V 2003 Current Appl. Phys. 3 2 [16] Zhaoxin W, Liduo W, Haifeng W et al 2006 Phys. Rev. B 74 16 [17] Mahapatro A K and Ghosh S 2002 Appl. Phys. Lett. 80 25 [18] Campbell I H and Smith D L 1999 Appl. Phys. Lett. 74 4 [19] Rajesh K R, Varghese S and Menon C S 2007 J. Phys. Chem. Solids 68 4 [20] Neanmen D A 2003 Semiconductor Physics and Devices: Basic Principles (Beijing: Tsinghua University Press) p 327