Modelling Debye Dielectric Relaxation in Monohydroxy Alcohols
Li-Na Wang1,2 , Xing-Yu Zhao1,2 , Yi-Neng Huang1,2**
1 National Laboratory of Solid State Microstructures, School of Physics, Nanjing University, Nanjing 2100932 Xinjiang Laboratory of Phase Transitions and Microstructures in Condensed Matters, College of Physical Science and Technology, Yili Normal University, Yining 835000
Abstract ：The Debye relaxation of dielectric spectroscopy exists extensively in monohydroxy alcohols. We model the relaxation based on the infinite-pseudospin-chain Ising model and the Glauber dynamics, and the corresponding complex permittivity is obtained. The model results are in good agreement with the experimental data of 3,7-dimethyl-1-octanol, 2-ethyl-1-hexanol and 5-methyl-2-hexanol in a wide temperature range. Moreover, in the model parameters, the sum of the mean-field interaction energy and two times the orientation is nearly twice the hydrogen bond energy, which further states the rationality of this model.
收稿日期: 2019-06-25
出版日期: 2019-08-23
:
77.22.Ch
(Permittivity (dielectric function))
82.30.Rs
(Hydrogen bonding, hydrophilic effects)
61.20.Gy
(Theory and models of liquid structure)
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2019, Vol. 36 
