| ATOMIC AND MOLECULAR PHYSICS |
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Quantum Engineering of Helical Charge Migration in HCCI |
| ChunMei Liu1, Jörn Manz2,3,4*, Huihui Wang3,4, and Yonggang Yang3,4* |
1Crystal Physics Research Center, College of Science, Nanjing University of Posts and Telecommunications, Nanjing 210023, China
2Institut für Chemie und Biochemie, Freie Universität Berlin, 14195 Berlin, Germany
3State Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, China
4Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan 030006, China
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| Cite this article: |
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ChunMei Liu, Jörn Manz, Huihui Wang et al 2022 Chin. Phys. Lett. 39 123402 |
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Abstract Electronic charge of molecules can move on time scales when the nuclei stand practically still, from few hundreds of attoseconds to few femtoseconds. This ultrafast process is called “charge migration”. A typical consequence is rapid change of electronic dipole, which points to the center of charge. Corresponding linear (one-dimensional, 1D) and planar (2D) dipolar motions have already been well documented. Here we construct the first case of charge migration which causes chiral 3D dipolar motion, specifically along a helix about oriented iodo-acetylene (HCCI). Quantum dynamics simulations show that this can be induced by well-designed laser pulses.
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Received: 11 October 2022
Editors' Suggestion
Published: 22 November 2022
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| PACS: |
34.50.Gb
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(Electronic excitation and ionization of molecules)
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82.53.-k
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(Femtochemistry)
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31.70.Hq
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(Time-dependent phenomena: excitation and relaxation processes, and reaction rates)
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32.80.Qk
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(Coherent control of atomic interactions with photons)
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