| CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES |
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Thermal Characteristics of PVA-PANI-ZnS Nanocomposite Film Synthesized by Gamma Irradiation Method |
| Afarin Bahrami1**, Kasra Behzad2, Nastaran Faraji3, Alireza Kharazmi4** |
1Department of Physics, Islamshahr Branch, Islamic Azad University, Islamshahr, Iran
2Department of Physics, Shahr-e-Qods Branch, Islamic Azad University, Tehran, Iran
3School of Materials Science and Engineering, UNSW Australia, Sydney, NSW, Australia
4School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia
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| Cite this article: |
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Afarin Bahrami, Kasra Behzad, Nastaran Faraji et al 2018 Chin. Phys. Lett. 35 117802 |
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Abstract Gamma irradiation is employed for in situ preparation of PVA-PANI-ZnS nanocomposite. The irradiation dose is varied from 10 to 40 kGy at 10 kGy intervals. The XRD result confirms the formation of crystalline phases corresponding to ZnS nanoparticles, PVA and PANI. Field emission scanning electron microscopy shows the formation of agglomerated PANI along the PVA backbone, within which the ZnS nanoparticles are dispersed. UV-visible spectroscopy is conducted to measure the transmittance spectra of samples revealing the electronic absorption characteristics of ZnS and PANI nanoparticles. Photo-acoustic (PA) setup is installed to investigate the thermal properties of samples. The PA spectroscopy indicates a high value of thermal diffusivity for samples due to the presence of ZnS and PANI nanoparticles. Moreover, at higher doses, the more polymerization and formation of PANI and ZnS nanoparticles result in enhancement of thermal diffusivity.
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Received: 23 June 2018
Published: 23 October 2018
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| PACS: |
78.67.Sc
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(Nanoaggregates; nanocomposites)
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82.35.-x
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(Polymers: properties; reactions; polymerization)
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66.30.Xj
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(Thermal diffusivity)
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