| CONDENSED MATTER: STRUCTURE, MECHANICAL AND THERMAL PROPERTIES |
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Phase Transition and Negative Thermal Expansion Property of ZrMnMo$_{3}$O$_{12}$ |
| Xiang-Hong Ge1,2, Yan-Chao Mao1, Lin Li1, Li-Ping Li1, Na Yuan1, Yong-Guang Cheng1, Juan Guo1, Ming-Ju Chao1, Er-Jun Liang1** |
1College of Physical Science and Engineering, Key Laboratory of Materials Physics (Ministry of Education), Zhengzhou University, Zhengzhou 450052
2Zhongyuan University of Technology, College of Science, Zhengzhou 450007
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| Cite this article: |
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Xiang-Hong Ge, Yan-Chao Mao, Lin Li et al 2016 Chin. Phys. Lett. 33 046503 |
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Abstract A novel material of ZrMnMo$_{3}$O$_{12}$ with negative thermal expansion is presented. The phase transition temperature and coefficient of thermal expansion (CTE) are investigated by temperature-dependent x-ray diffraction and Raman spectra. It is shown that ZrMnMo$_{3}$O$_{12}$ adopts monoclinic structure with space group $P21/a$ (No. 14) from 298 to 358 K and transforms to orthorhombic with space group $Pnma$ (No. 62) above 363 K. The linear CTE obtained from the results of XRD refinement is $-2.80\times10^{-6}$ K$^{-1}$ from 363 to 873 K. The CTE of the bulk cylinder ceramic measured by a thermal dilatometer is $-4.7\times10^{-6}$ K$^{-1}$ from 373 to 773 K approximatively.
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Received: 27 November 2015
Published: 29 April 2016
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| PACS: |
65.40.De
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(Thermal expansion; thermomechanical effects)
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61.50.Ks
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(Crystallographic aspects of phase transformations; pressure effects)
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78.30.-j
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(Infrared and Raman spectra)
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