CONDENSED MATTER: STRUCTURE, MECHANICAL AND THERMAL PROPERTIES |
|
|
|
|
Time-Resolved Measurements of the Adsorption/Desorption of Rb Atoms on Octadecyltrichlorosilane Coated Surfaces |
LIAO Kang-Jia1,2, WANG Mei-Ling1,2, ZHANG Gui-Ying1,2, ZHAO Kai-Feng1,2** |
1Institute of Modern Physics, Department of Nuclear Science and Technology, Fudan University, Shanghai 200433 2Applied Ion Beam Physics Laboratory (Ministry of Education), Fudan University, Shanghai 200433
|
|
Cite this article: |
LIAO Kang-Jia, WANG Mei-Ling, ZHANG Gui-Ying et al 2015 Chin. Phys. Lett. 32 076801 |
|
|
Abstract We carry out the first time-resolved measurement of Rb atoms desorbing from octadecyltrichlorosilane coated surfaces by polarizing the atoms near the surface using an evanescent wave pump pulse and watching the subsequent intensity change of another evanescent wave probe beam, and find the mean adsorption (dwell) time to be about 400 ns at a cell body temperature of 112°C. The adsorption energy is found to be 0.19 eV from the surface temperature dependence of the adsorption time. This method can be extended to study the adsorption/desorption process of other alkali atoms on other surfaces of transparent substrates with an ultimate time resolution limited by the flight time of atoms in the evanescent wave which is of the order of nanoseconds.
|
|
Received: 20 April 2015
Published: 30 July 2015
|
|
PACS: |
68.43.Nr
|
(Desorption kinetics)
|
|
32.80.Xx
|
(Level crossing and optical pumping)
|
|
42.25.Gy
|
(Edge and boundary effects; reflection and refraction)
|
|
|
|
|
[1] Afanasiev A E, Melentiev P N and Balykin V I 2007 JETP Lett. 86 172 [2] Gozzini A, Mango F, Xu J H, Alzetta G, Maccarrone F and Bernheim R A 1993 Il Nuovo Cimento Soc. Ital. Fis. D 15 709 [3] Chevrollier M, Fichet M, Oria M, Rahmat G, Bloch D and Ducloy M 1992 J. Phys. II (Paris) 2 631 [4] Bordo V G, Loerke J and Rubahn H G 2001 Phys. Rev. Lett. 86 1490 [5] Bouchiat M A and Brossel J 1966 Phys. Rev. 147 41 [6] Brewer R G 1963 J. Chem. Phys. 38 3015 [7] Corsini E P, Karaulanov T, Balabas M and Budker D 2013 Phys. Rev. A 87 022901 [8] Yi Y W, Robinson H G, Knappe S, Maclennan J E, Jones C D, Zhu C, Clark N A and Kitching J 2008 J. Appl. Phys. 104 023534 [9] Stephens M, Rhodes R and Wieman C 1994 J. Appl. Phys. 76 3479 [10] Zhao K F, Schaden M and Wu Z 2009 Phys. Rev. Lett. 103 073201 [11] Budker D and Kimball D F 2013 Optical Mmagnetometry (New York: Cambridge University Press) [12] Atutov S N and Plekhanov A I 2015 J. Exp. Theor. Phys. 120 1 [13] De Freitas H N, Oria M and Chevrollier M 2002 Appl. Phys. B 75 703 [14] Zhang G Y, Wei L H, Wang M L and Zhao K F 2015 J. Appl. Phys. 117 043106 |
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|