| ATOMIC AND MOLECULAR PHYSICS |
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Stereodynamics Study of Li+HF/DF/TF→LiF+H/D/T Reactions on X2A' Potential Energy Surface |
| TAN Rui-Shan, LIU Xin-Guo**, HU Mei |
| College of Physics and Electronics, Shandong Normal University, Jinan 250014 |
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| Cite this article: |
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TAN Rui-Shan, LIU Xin-Guo, HU Mei 2012 Chin. Phys. Lett. 29 123101 |
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Abstract The product rotational polarizations of reactions Li+HF/DF/TF at different collision energies are calculated using the quasi-classical trajectory method based on a new potential energy surface constructed by Aguado and Paniagua [J. Chem. Phys. 119 (2003) 10088]. We investigate the P(θr) distributions describing the k–j' correlation, the P(φr) distributions describing the k–k'–j' correlation, and the four polarization-dependent generalized differential cross sections. Furthermore, we compare the influences of mass factor and collision energy in detail and find that the isotope substitution has more impact on the distribution of the product's angular momentum vectors than the collision energy.
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Received: 08 October 2012
Published: 04 March 2013
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| PACS: |
31.15.ap
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(Polarizabilities and other atomic and molecular properties)
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31.15.at
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(Molecule transport characteristics; molecular dynamics; electronic structure of polymers)
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34.50.Lf
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(Chemical reactions)
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