Chin. Phys. Lett.  2010, Vol. 27 Issue (11): 114208    DOI: 10.1088/0256-307X/27/11/114208
FUNDAMENTAL AREAS OF PHENOMENOLOGY(INCLUDING APPLICATIONS) |
A Novel Ce3+/Tb3+ Codoped Phosphate Glass as Down-Shifting Materials for Enhancing Efficiency of Solar Cells
HE Dong-Bing1,2**, YU Chun-Lei1, CHENG Ji-Meng1, LI Shun-Guang1, HU Li-Li1
1Key Laboratory of High Power Laser Materials, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800
2Graduate School of Chinese Academy of Sciences, Beijing 100049
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HE Dong-Bing, YU Chun-Lei, CHENG Ji-Meng et al  2010 Chin. Phys. Lett. 27 114208
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Abstract For the purpose of improving conversion efficiency of solar cells by applying the effect of the wavelength conversion of rare earth ions, photo-luminescence and excitation spectrums of Ce3+−Tb3+ doped phosphate glass are investigated. Results show that incorporating Ce3+ ions to Tb3+−doped phosphate glass can greatly increase the absorption coefficient in the range 300-400 nm and then the energy transfer (ET) from Ce3+ to Tb3+ occurs. In addition, increasing Tb3+ concentration in Ce3+/Tb3+ co−doped phosphate glass can greatly enhance the ET efficiency and 545 nm emission intensity. This shows that Ce3+/Tb3+ co-doped phosphate glass would be a promising down-shifting material for enhancing the efficiency of solar cells.
Keywords: 42.70.Ce      78.20.Ci      42.70.Hj     
Received: 24 March 2010      Published: 22 October 2010
PACS:  42.70.Ce (Glasses, quartz)  
  78.20.Ci (Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity))  
  42.70.Hj (Laser materials)  
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https://cpl.iphy.ac.cn/10.1088/0256-307X/27/11/114208       OR      https://cpl.iphy.ac.cn/Y2010/V27/I11/114208
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HE Dong-Bing
YU Chun-Lei
CHENG Ji-Meng
LI Shun-Guang
HU Li-Li
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