CONDENSED MATTER: STRUCTURE, MECHANICAL AND THERMAL PROPERTIES |
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Identification of Acceptor States in Li-N Dual-Doped p-Type ZnO Thin Films |
ZHANG Yin-Zhu1, LU Jian-Guo1, YE Zhi-Zhen1, HE Hai-Ping1, CHEN Lan-Lan2, ZHAO Bing-Hui1 |
1State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 3100272School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798 |
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Cite this article: |
ZHANG Yin-Zhu, LU Jian-Guo, YE Zhi-Zhen et al 2009 Chin. Phys. Lett. 26 046103 |
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Abstract Li-N dual-doped p-type ZnO (ZnO:(Li,N)) thin films are prepared by pulsed laser deposition. The optical properties are studied using temperature-dependent photoluminescence. The LiZn-NO complex acceptor with an energy level of 138meV is identified from the free-to-neutral-acceptor (e, A0) emission. The Haynes factor is about 0.087 for the LiZn-NO complex acceptor, with the acceptor bound-exciton binding energy of 12meV. Another deeper acceptor state located at 248meV, also identified from the (e, A0) emission, is attributed to zinc vacancy acceptor. The two acceptor states might both contribute to the observed p-type conductivity in ZnO:(Li,N).
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Keywords:
61.72.Vv
73.61.Ga
81.15.Fg
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Received: 03 October 2008
Published: 25 March 2009
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