Chin. Phys. Lett.  2009, Vol. 26 Issue (8): 088102    DOI: 10.1088/0256-307X/26/8/088102
CROSS-DISCIPLINARY PHYSICS AND RELATED AREAS OF SCIENCE AND TECHNOLOGY |
Excellent Passivation of p-Type Si Surface by Sol-Gel Al2O3 Films
XIAO Hai-Qing1, ZHOU Chun-Lan2, CAO Xiao-Ning2, WANG Wen-Jing2, ZHAO Lei2, LI Hai-Ling2, DIAO Hong-Wei2
1Institute of Industrial Product Inspection, Chinese Academy of Inspection and Quarantine, Beijing 1001232Solar Cell Technology Laboratory, Institute of Electrical Engineering, Chinese Academy of Sciences, PO Box 2703, Beijing 100190
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XIAO Hai-Qing, ZHOU Chun-Lan, CAO Xiao-Ning et al  2009 Chin. Phys. Lett. 26 088102
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Abstract Al2O3 films with a thickness of about 100nm synthesized by spin coating and thermally treated are applied for field-induced surface passivation of p-type crystalline silicon. The level of surface passivation is determined by techniques based on photoconductance. An effective surface recombination velocity below 100cm/s is obtained on 10Ω·cm p-type c-Si wafers (Cz Si). A high density of negative fixed charges in the order of 1012cm-2 is detected in the Al2O3 films and its impact on the level of surface passivation is demonstrated experimentally. Furthermore, a comparison between the surface passivation achieved for thermal SiO2 and plasma enhanced chemical vapor deposition SiNx:H films on the same c-Si is presented. The high negative fixed charge density explains the excellent passivation of p-type c-Si by Al2O3.
Keywords: 81.65.Rv      77.84.-s      84.60.Jt     
Received: 13 February 2009      Published: 30 July 2009
PACS:  81.65.Rv (Passivation)  
  77.84.-s (Dielectric, piezoelectric, ferroelectric, and antiferroelectric materials)  
  84.60.Jt (Photoelectric conversion)  
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https://cpl.iphy.ac.cn/10.1088/0256-307X/26/8/088102       OR      https://cpl.iphy.ac.cn/Y2009/V26/I8/088102
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XIAO Hai-Qing
ZHOU Chun-Lan
CAO Xiao-Ning
WANG Wen-Jing
ZHAO Lei
LI Hai-Ling
DIAO Hong-Wei
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