Chin. Phys. Lett.  2007, Vol. 24 Issue (5): 1331-1334    DOI:
Original Articles |
Miscibility of Two Components in a Binary Mixture of 9-Phenyl Anthracene Mixed with Stearic Acid or Polymethyl Methacrylate at Air--Water Interface
P. K. Paul;Md. N. Islam;D. Bhattacharjee;S. A. Hussain
Department of Physics, Tripura University, Suryamaninagar-799130, Tripura, India
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P. K. Paul, Md. N. Islam, D. Bhattacharjee et al  2007 Chin. Phys. Lett. 24 1331-1334
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Abstract We report the miscibility characteristics of two components in a binary mixture of 9-phenyl anthracene (PA) mixed with stearic acid (SA) or polymethyl methacrylate (PMMA). The behaviour of surface pressure versus area per molecule isotherms reveal that the area per molecule decreases systematically with increasing molefractions of PA. The characteristics of areas per molecule versus molefractions and collapse pressure vs molefraction indicate that various interactions involved among the sample and matrix molecules. The interaction scheme is found to change with the change in surface pressure and molefraction of mixing. Scanning electron microscopic study confirms the aggregation of PA molecules in the mixed films.
Keywords: 68.37.-d      68.18.-g      68.47.Pe     
Received: 25 December 2006      Published: 23 April 2007
PACS:  68.37.-d (Microscopy of surfaces, interfaces, and thin films)  
  68.18.-g (Langmuir-Blodgett films on liquids)  
  68.47.Pe (Langmuir-Blodgett films on solids; polymers on surfaces; biological molecules on surfaces)  
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https://cpl.iphy.ac.cn/       OR      https://cpl.iphy.ac.cn/Y2007/V24/I5/01331
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Articles by authors
P. K. Paul
Md. N. Islam
D. Bhattacharjee
S. A. Hussain
[1] Ulman A 1991 An Introduction to Ultrathin Organic Films: FromLangmuir--Blodgett Films of Self Assemblies (New York: Academic)
[2] Petty M C 1996 Langmuir--Blodgett Films: An Introduction(Cambridge: Cambridge University Press)
[3] Acharya S, Bhattacharjee D, Sarkar J and Talapatra G B 2004 Chem. Phys. Letts. 393 1
[4] Hussain S A, Paul P K and Bhattacharjee D 2006 J. ColloidInterface Sci. 299 785
[5] Deb S, Biswas S, Hussain S A and Bhattacharjee D 2005 Chem. Phys. Lett. 405 323
[6] Hussain S A, Deb S and Bhattacharjee D 2005 J. Lumin. 114 197
[7] Zaidi N A, Bryce M R and Cross G H 2000 TetrahedronLett. 41 4645
[8] Birdi K S 1989 Lipid and Biopolymer Monolayer at LiquidInterfaces (New York: Plenum)
[9] Gaines G L Jr 1966 Insoluble Monolayers at Liquid-GasInterface (New York: Wiley Interscience)
[10] Paul S, Pearson C, Molloy A, Cousins M A, Green M, Kollipoulou S,Dimitrakis P, Normand P, Tsoukalas D and Petty M C 2003 NanoLett. 3/4 533
[11] Holman J, Neivandt D J et al 2004 Chem. Phys. Lett. 386 60
[12] Hussain S A, Deb S, Biswas S and Bhattacharjee D 2005 Spectrochim. Acta A 61 2448
[13] Dorfler H D 1990 Adv. Colloid Interface Sci. 31 1
[14] Barnes G T 1991 J. Colloid Interface Sci. 144 299
[15] Hussain S A, Paul P K and Bhattacharjee D 2006 J. Phys.Chem. Solids 67 2542
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