Oxygen Ion Implantation Enhanced Silicon-Vacancy Photoluminescence and n-Type Conductivity of Ultrananocrystalline Diamond Films
HU Xiao-Jun** , LI Nian
College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014
Abstract :We report the enhanced silicon-vacancy (Si-V) photoluminescence (PL) intensity and n-type conductivity of ultrananocrystalline diamond (UNCD) films by oxygen ion (O+ ) implantation. With O+ dose increasing from 1014 to 1015 cm?2 , the PL intensity and n-type conductivity significantly increase by 6 and 45 times, respectively, after 1000°C annealing. The secondary ion mass spectroscopy mapping measurements show that the content of oxygen is larger in the zone, which has larger content of silicon, indicating that oxygen tends to adhere to silicon. It is suggested that oxygen related Si-V defects are formed, which will enhance the PL intensity and n-type conductivity of UNCD films.
收稿日期: 2013-04-25
出版日期: 2013-11-21
:
81.05.ug
(Diamond)
78.55.Ap
(Elemental semiconductors)
68.55.Ln
(Defects and impurities: doping, implantation, distribution, concentration, etc.)
[1] Brien J L 2007 Science 318 1567 [2] Vlasov I I, Barnard A S, Ralchenko V G, Lebedev O I, Kanzyuba M V, Saveliev A V, Konov V I and Goovaerts E 2009 Adv. Mater. 21 808 [3] Mohan N, Tzeng Y K, Yang L L, Chen Y Y, Hui Y Y, Fang C Y and Chang H C 2010 Adv. Mater. 22 843 [4] Faklaris O, Garrot D, Joshi V, Druon F, Boudou J P, Sauvage T, Georges P, Curmi P A and Treussart F 2008 Small 4 2236 [5] Kurtsiefer C, Mayer S, Zarda P and Weinfurter H 2000 Phys. Rev. Lett. 85 290 [6] Rabeau J R, Chin Y L, Prawer S, Jelezko F, Gaebel T and Wrachtrup J 2005 Appl. Phys. Lett. 86 131926 [7] Wang C L, Kurtsiefer C, Weinfurter H and Burchard B 2006 J. Phys. B: At. Mol. Opt. Phys. 39 37 [8] Neu E, Hepp C, Hauschild M, Gsell S, Fischer M, Sternschulte H, Steinmüller-Nethl D, Schreck M and Becher C 2013 New J. Phys. 15 043005 [9] Neu E, Steinmetz D, Riedrich-M?ller J, Gsell S, Fischer M, Schreck M and Becher C 2011 New J. Phys. 13 025012 [10] Neu E, Guldner F, Arend C, Liang Y J, Ghodbane S, Sternschulte H, Steinmueller-Nethl D, Krueger A and Becher C 2013 J. Appl. Phys. 113 203507 [11] Mares J J, Hubik P, Kristofik J, Kindl D, Fanta M, Nesladek M, Williams O and Gruen D M 2006 Appl. Phys. Lett. 88 092107 [12] Beloborodov I S, Zapol P, Gruen D M and Curtiss L A 2006 Phys. Rev. B 74 235434 [13] Hu Q, Hirai M, Joshi R K and Kumar A 2009 J. Phys. D: Appl. Phys. 42 025301 [14] Williams O A 2006 Semicond. Sci. Technol. 21 R49 [15] Hu X J, Ye J S, Liu H J, Shen Y G, Chen X H and Hu H 2011 J. Appl. Phys. 109 053524 [16] Hu X J, Ye J S, Hu H, Chen X H and Shen Y G 2011 Appl. Phys. Lett. 99 131902 [17] Birrell J, Gerbi J E, Auciello O, Gibson J M, Gruen D M and Carlisle J A 2003 J. Appl. Phys. 93 5606 [18] Zapol P, Sternberg M, Curtiss L A, Frauenheim Th and Gruen D M 2002 Phys. Rev. B 65 045403 [19] Goss J P, Briddon P R, Rayson M J, Sque S J and Jones R 2005 Phys. Rev. B 72 035214 [20] Gilkes K W R, Sands H S, Batchelder D N, Robertson J and Milne W I 1997 Appl. Phys. Lett. 70 1980 [21] Barnard A S, Vlasov I I and Ralchenko V G 2009 J. Mater. Chem. 19 360 [22] Hu X J, Dai Y B, Li R B, Shen H S and He X C 2002 Solid State Commun. 122 45 [23] Orwa J O, Ganesan K, Newnham J, Santori C, Barclay P, Fu K M C, Beausoleil R G, Aharonovich I, Fairchild B A, Olivero P, Greentree A D and Prawer S 2012 Diamond Relat. Mater. 24 6 [24] Zhou X T, Sham T K, Wu Y, Chong Y M, Bello I, Lee S T, Heigl F, Regier T and Blyth R I 2007 J. Am. Chem. Soc. 129 1476 [25] Polman A 1997 J. Appl. Phys. 82 1 [26] Michel J, Benton J L, Ferrante R F, Jacobson D C, Eaglesham D J, Fitzgerald E A, Xie Y H, Poate J M and Kimerling L C 1991 J. Appl. Phys. 70 2672
[1]
. [J]. 中国物理快报, 2022, 39(3): 36801-.
[2]
. [J]. 中国物理快报, 2021, 38(2): 28102-.
[3]
. [J]. 中国物理快报, 0, (): 68102-.
[4]
. [J]. 中国物理快报, 2020, 37(6): 68102-.
[5]
. [J]. 中国物理快报, 2018, 35(7): 78101-.
[6]
. [J]. 中国物理快报, 2016, 33(08): 88101-088101.
[7]
FAN Xiao-Hong,XU Bin**,NIU Zhen,ZHAI Tong-Guang,TIAN Bin. Fine Structural and Carbon Source Analysis for Diamond Crystal Growth using an Fe-Ni-C System at High Pressure and High Temperature [J]. 中国物理快报, 2012, 29(4): 48102-048102.
[8]
YANG Yan-Ning;ZHANG Zhi-Yong**;ZHANG Fu-Chun;DONG Jun-Tang;ZHAO Wu;ZHAI Chun-Xue;ZHANG Wei-Hu. The Field Emission Characteristics of Titanium-Doped Nano-Diamonds [J]. 中国物理快报, 2012, 29(1): 18103-018103.
[9]
ZHANG Chun-Mei;ZHENG Yan-Bin;JIANG Zhi-Gang;LV Xian-Yi;HOU Xue;HU Shuang;LIU Jun-Wei. Effect of CO2 Addition on Preparation of Diamond Films by Direct-Current Hot-Cathode Plasma Chemical Vapor Deposition Method [J]. 中国物理快报, 2010, 27(8): 88103-088103.
[10]
WANG Qi-Liang;LÜXian-Yi;LI Liu-An;CHENG Shao-Heng;LI Hong-Dong. Growth and Characteristics of Freestanding Hemispherical Diamond Films by Microwave Plasma Chemical Vapor Deposition [J]. 中国物理快报, 2010, 27(4): 47802-047802.