Optical Oscillator Strengths of Hydrogen Bromide in the 4.5-20 eV Excitation Energy Region
LI Wen-Bin, ZHU Lin-Fan, LIU Xiao-Jing, YUAN Zhen-Sheng, SUN Jian-Min, CHENG Hua-Dong, XU Ke-Zun
Hefei National Laboratory for Physical Sciences at Microscale and Laboratory of Bond-Selective Chemistry,
Department of Modern Physics, University of Science and Technology of China, Hefei 230027
Optical Oscillator Strengths of Hydrogen Bromide in the 4.5-20 eV Excitation Energy Region
LI Wen-Bin;ZHU Lin-Fan;LIU Xiao-Jing;YUAN Zhen-Sheng;SUN Jian-Min;CHENG Hua-Dong;XU Ke-Zun
Hefei National Laboratory for Physical Sciences at Microscale and Laboratory of Bond-Selective Chemistry,
Department of Modern Physics, University of Science and Technology of China, Hefei 230027
Abstract: The absolute optical oscillator strength density spectrum of HBr in the valence shell energy region of 4.5-20 eV has been determined by a high-resolution fast electron energy loss spectrometer. The optical oscillator strengths for the broad a3II + A1II dissociation peak and the discrete transitions of 3II1(v = 0) and C1II(v '= 0,1,2) are reported. It has been manifested clearly that the optical oscillator strengths of some transitions for the previous photoabsorption method are subject to severe line-saturation effects.
(Oscillator and band strengths, lifetimes, transition moments, and Franck-Condon factors)
引用本文:
LI Wen-Bin;ZHU Lin-Fan;LIU Xiao-Jing;YUAN Zhen-Sheng;SUN Jian-Min;CHENG Hua-Dong;XU Ke-Zun. Optical Oscillator Strengths of Hydrogen Bromide in the 4.5-20 eV Excitation Energy Region[J]. 中国物理快报, 2004, 21(4): 656-658.
LI Wen-Bin, ZHU Lin-Fan, LIU Xiao-Jing, YUAN Zhen-Sheng, SUN Jian-Min, CHENG Hua-Dong, XU Ke-Zun. Optical Oscillator Strengths of Hydrogen Bromide in the 4.5-20 eV Excitation Energy Region. Chin. Phys. Lett., 2004, 21(4): 656-658.