Absolute Generalized-Oscillator-Strength Measurement of C 1 s Preionization-Edge Electronic Excitations of C2F6
FAN Xiao-Wei1,3, LIAO Tian-He2, ZHANG Xian-Zhou1, GAO Jin-Hui1, WEI Jian-Yu1, K. T. Leung3
1Department of Physics, Henan Normal University, Xinxiang 453002
2Department of Physics, Zhengzhou Information Engineering University, Zhengzhou 450002
3Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada
Absolute Generalized-Oscillator-Strength Measurement of C 1 s Preionization-Edge Electronic Excitations of C2F6
FAN Xiao-Wei1,3;LIAO Tian-He2;ZHANG Xian-Zhou1;GAO Jin-Hui1;WEI Jian-Yu1;K. T. Leung3
1Department of Physics, Henan Normal University, Xinxiang 453002
2Department of Physics, Zhengzhou Information Engineering University, Zhengzhou 450002
3Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada
Abstract: Absolute generalized oscillator strengths (GOSs) for the C 1 s preionization-edge transitions at 295.4 eV and 297.7 eV in perfluoroethane have been determined as functions of energy loss and momentum transfer (K) at impact energy of 2.5 keV for the first time. The corresponding GOS profiles have been found to have the characteristic dipole-dominated shapes with a strong maximum at K = 0. The spectral features can be interpreted in terms of transitions terminating at the σ* (C-F) molecular orbital.
(Electronic excitation and ionization of molecules)
引用本文:
FAN Xiao-Wei;LIAO Tian-He;ZHANG Xian-Zhou;GAO Jin-Hui;WEI Jian-Yu;K. T. Leung. Absolute Generalized-Oscillator-Strength Measurement of C 1 s Preionization-Edge Electronic Excitations of C2F6
[J]. 中国物理快报, 2004, 21(3): 478-480.
FAN Xiao-Wei, LIAO Tian-He, ZHANG Xian-Zhou, GAO Jin-Hui, WEI Jian-Yu, K. T. Leung. Absolute Generalized-Oscillator-Strength Measurement of C 1 s Preionization-Edge Electronic Excitations of C2F6
. Chin. Phys. Lett., 2004, 21(3): 478-480.