Blue-Light Emission from Nanocrystalline La0.5Na0.5TiO3
ZHANG Wei-feng1, ZHANG Xing-tang2, YIN Zhen1, ZHANG Ming-sheng1, MA Guo-hong2, DU Zu-liang2
1Center for Materials Analysis and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093
2Department of Physics, He’nan University, Kaifeng 475001
Blue-Light Emission from Nanocrystalline La0.5Na0.5TiO3
1Center for Materials Analysis and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093
2Department of Physics, He’nan University, Kaifeng 475001
Abstract: Nanocrystalline La0.5Na0.5TiO3 powders were prepared by the stearic acid-gel method, and the grain sizes could be controlled by varying annealing temperatures. The sizes were determined to be from 14 to 50nm using Scherrer's formula. A very strong blue-light emission band around 480nm was clearly observed in the nano-sized La0.5Na0.5TiO3 with a grain size of 14nm at room temperature. Also, nano-size effects on the luminescence properties were investigated. These results could be explained with the aid of a self-trapped exciton model.