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A Statistical Theory for Hydrogen Bonding Networks: One Component Case |
| WANG Hai-Jun1;BA Xin-Wu1;ZHAO Min1;LI Ze-Sheng2 |
| 1Department of Chemistry, Hebei University, Baoding 071002
2Institute of Theoretical Chemistry and State Key Laboratory of Theoretical and Computational Chemistry, Jilin University, Changchun 130023
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| Cite this article: |
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WANG Hai-Jun, BA Xin-Wu, ZHAO Min et al 2000 Chin. Phys. Lett. 17 16-18 |
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Abstract The theory of reversible gelation is shown to be applicable to the hydrogen bonding system by analyzing their similarities in statistical viewpoint. The size distribution of hydrogen bonding clusters, the gelation condition and the generalized scaling law can be obtained directly. These results show that such a system can undergo phase transition process. Furthermore, a relationship between Gibbs free energy of forming hydrogen bond and conversions of groups is given. As an example, the chemical shift of OH groups is considered.
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| Keywords:
35.20.Gs
82.20.Db
82.30.Nr
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Published: 01 January 2000
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| PACS: |
35.20.Gs
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82.20.Db
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(Transition state theory and statistical theories of rate constants)
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82.30.Nr
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(Association, addition, insertion, cluster formation)
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