A Simple Deposition Method for Self-Assembling Single Crystalline Hybrid Perovskite Nanostructures
Wen-Rong Xie, Bin Liu** , Tao Tao, Guo-Gang Zhang, Bao-Hua Zhang, Zi-Li Xie** , Peng Chen, Dun-Jun Chen, Rong Zhang
School of Electronic Science and Engineering, Nanjing University, Nanjing 210093
Abstract ：A sequential deposition method is developed, where the hybrid organic–inorganic halide perovskite (CH$_{3}$NH$_{3}$Pb (I$_{1-x}$Br$_{x}$)$_{3}$) is synthesized using precursor solutions containing CH$_{3}$NH$_{3}$I and PbBr$_{2}$ with different mole ratios and reaction times. The perovskite achieved here is quite stable in the atmosphere for a relatively long time without noticeable degradation, and the perovskite nanowires are proved to be single crystalline structure, based on transmission electron microscopy. Furthermore, strong red photoluminescence from perovskite is observed in the wavelength range from 746 nm to 770 nm with the increase of the reaction time, on account of the exchanges between I$^{-}$ ions and Br$^{-}$ ions in the perovskite crystal. Lastly, the influences of concentration and reaction time of the precursor solutions are discussed, which are important for evolution of hybrid perovskite from nanocuboid to nanowire and nanosheet.
收稿日期: 2017-02-27
出版日期: 2017-05-23
:
81.10.-h
(Methods of crystal growth; physics and chemistry of crystal growth, crystal morphology, and orientation)
81.07.Pr
(Organic-inorganic hybrid nanostructures)
61.82.Rx
(Nanocrystalline materials)
61.46.Hk
(Nanocrystals)
引用本文:
. [J]. 中国物理快报, 2017, 34(6): 68103-.
链接本文:
https://cpl.iphy.ac.cn/CN/10.1088/0256-307X/34/6/068103
或
https://cpl.iphy.ac.cn/CN/Y2017/V34/I6/68103
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