摘要Using a U(2) algebraic model the fundamental stretching vibrations of copper octaethyl porphyrin and magnesium octaethyl porphyrin are calculated for 24 vibrational bands. The locality parameter ξ confirms the highly local behavior of the stretching modes of these porphyrin molecules. The model Hamiltonian so constructed appears to describe the vibrational energy levels accurately.
Abstract：Using a U(2) algebraic model the fundamental stretching vibrations of copper octaethyl porphyrin and magnesium octaethyl porphyrin are calculated for 24 vibrational bands. The locality parameter ξ confirms the highly local behavior of the stretching modes of these porphyrin molecules. The model Hamiltonian so constructed appears to describe the vibrational energy levels accurately.
Srinivasa Rao Karumuri. Vibrational Spectra of Distorted Structure Molecules by Using Lie Algebraic Techniques: an Application to Copper and Magnesium Octaethyl Porphyrin[J]. 中国物理快报, 2010, 27(10): 103301-103301.
Srinivasa Rao Karumuri. Vibrational Spectra of Distorted Structure Molecules by Using Lie Algebraic Techniques: an Application to Copper and Magnesium Octaethyl Porphyrin. Chin. Phys. Lett., 2010, 27(10): 103301-103301.
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