摘要The spin-Hamiltonian parameters obtained from EPR studies of the VO2+ ion in different diamagnetic host lattices are used to estimate the ground state wavefunctions. These are of dxy type with admixture of the excited states dx2-y2, dyz and dxz. The hyperfine interaction parameter and Fermi contact term for the VO2+ doped crystals are determined using the coefficients of the ground state. The various parameters are correlated to the ligand properties of the complexes.
Abstract：The spin-Hamiltonian parameters obtained from EPR studies of the VO2+ ion in different diamagnetic host lattices are used to estimate the ground state wavefunctions. These are of dxy type with admixture of the excited states dx2-y2, dyz and dxz. The hyperfine interaction parameter and Fermi contact term for the VO2+ doped crystals are determined using the coefficients of the ground state. The various parameters are correlated to the ligand properties of the complexes.
Ram Kripal;Santwana Shukla. C4v Symmetry Crystal Field and Ground State Wavefunction of the VO2+ Ion[J]. 中国物理快报, 2009, 26(8): 87601-087601.
Ram Kripal, Santwana Shukla. C4v Symmetry Crystal Field and Ground State Wavefunction of the VO2+ Ion. Chin. Phys. Lett., 2009, 26(8): 87601-087601.
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