Hyperspherical Calculations on Electron Affinity and Geometry for Li- and Na-

  • Using a model potential to describe the interaction between the core and the valence electron, we perform hyperspherical calculations for electron affinity and geometry of the weakly bound Li- and Na- systems. In our calculation, channel functions are expanded in terms of B-splines. Using the special properties of B-splines, we make the knot distributions more precisely, characterizing the behaviour of channel functions. This improves the convergence greatly. Our results are in good agreement with the other theoretical and experimental values.
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