Relativistic Multichannel Treatment of Ionic Rydberg States of Lanthanum

Ionic Rydberg energy levels of lanthanum are calculated from first principles by relativistic multichannel theory within the framework of multichannel quantum defect theory. The present calculated results are in better agreement with the experimental measurements than the previous calculations J. Phys. B 34(2001)369 due to the consideration of dynamical polarizations. Moreover, in the experimental spectra achieved by a five-laser resonance excitation via the intermediate state 5d6d³ F₂, a series of weak ionic Rydberg states and some of perturbing states are found and assigned in this work.