The Complex Magnetism in the Breathing Pyrochlore LiIn(CrRh)O
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Abstract
We perform a detailed investigation of the new 'breathing' pyrochlore compound LiInCrO through Rh substitution with measurements of magnetic susceptibility, specific heat, and x-ray powder diffraction. The antiferromagnetic phase of LiInCrO is found to be slowly suppressed with increasing Rh, up to the critical concentration of where the antiferromagnetic phase is still observed with the peak in specific heat K, slightly lower than K for the compound. From the measurements of magnetization we also uncover evidence that substitution increases the amount of frustration. Comparisons are made with the LiGaInCrO system as well as other frustrated pyrochlore-related materials and comparable amounts of frustration are found. The results of this work show that the engineered breathing pyrochlores present an important method to further understand the complex magnetism in frustrated systems. -
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References
[1] Gardner J S et al. 2010 Rev. Mod. Phys. 82 53 doi: 10.1103/RevModPhys.82.53[2] Bramwell S T and Gingras M J P 2001 Science 294 1495 doi: 10.1126/science.1064761[3] Raju N P et al. 1992 Phys. Rev. B 46 5405 doi: 10.1103/PhysRevB.46.5405[4] Mandrus D et al. 2001 Phys. Rev. B 63 195104 doi: 10.1103/PhysRevB.63.195104[5] Yang B J and Kim Y B 2010 Phys. Rev. B 82 085111 doi: 10.1103/PhysRevB.82.085111[6] Yonezawa S et al. 2004 J. Phys. Soc. Jpn. 73 819 doi: 10.1143/JPSJ.73.819[7] Yonezawa S et al. 2004 J. Phys. Soc. Jpn. 73 1655 doi: 10.1143/JPSJ.73.1655[8] Yonezawa S et al. 2004 J. Phys.: Condens. Matter 16 L9 doi: 10.1088/0953-8984/16/3/L01[9] Gaertner H R 1930 Neues Jb. Mineralog. 61 1[10] Greedan J E et al. 1986 Solid State Commun. 59 895 doi: 10.1016/0038-10988690652-6[11] Sanders M B et al. 2016 J. Mater. Chem. C 4 541 doi: 10.1039/C5TC03798K[12] Okamoto Y et al. 2013 Phys. Rev. Lett. 110 097203 doi: 10.1103/PhysRevLett.110.097203[13] Tanaka Y et al. 2014 Phys. Rev. Lett. 113 227204 doi: 10.1103/PhysRevLett.113.227204[14] Lee S et al. 2016 Phys. Rev. B 93 174402 doi: 10.1103/PhysRevB.93.174402[15] Okamoto Y et al. 2015 J. Phys. Soc. Jpn. 84 043707 doi: 10.7566/JPSJ.84.043707[16] Martinho H, Moreno N O, Sanjurjo J A, Rettori C, Gar? ia-Adeva A J, Huber D L, Oseroff S B, Ratcliff I I W, Cheong S W, Pagliuso P G, Sarrao J L and Martins G B 2001 J. Appl. Phys. 89 7050 doi: 10.1063/1.1358340[17] Larson A C and Von Dreele R B 2004 General Structure Analysis System Los Alamos National Laboratory Report LAUR p 86[18] Toby B H 2001 J. Appl. Crystallogr. 34 210 doi: 10.1107/S0021889801002242[19] Kimura K et al. 2014 Phys. Rev. B 90 060414R doi: 10.1103/PhysRevB.90.060414[20] Hagemann I S et al. 2001 Phys. Rev. Lett. 86 894 doi: 10.1103/PhysRevLett.86.894[21] Kanchanavatee N et al. 2011 Phys. Rev. B 84 245122 doi: 10.1103/PhysRevB.84.245122[22] Recio J M et al. 2001 Phys. Rev. B 63 184101 doi: 10.1103/PhysRevB.63.184101[23] Zhang L, Ji G F, Zhao F and Gong Z Z 2011 Chin. Phys. B 20 047102 doi: 10.1088/1674-1056/20/4/047102 -
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